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- W3044959356 endingPage "4129" @default.
- W3044959356 startingPage "4119" @default.
- W3044959356 abstract "Abstract A generalized, simple and efficient transfer hydrogenation of unsaturated bonds has been developed using HBPin and various proton reagents as hydrogen sources. The substrates, including alkenes, alkynes, aromatic heterocycles, aldehydes, ketones, imines, azo, nitro, epoxy and nitrile compounds, are all applied to this catalytic system. Various groups, which cannot survive under the Pd/C/H 2 combination, are tolerated. The activity of the reactants was studied and the trends are as follows: styrene>diphenylmethanimine>benzaldehyde>azobenzene>nitrobenzene>quinoline>acetophenone>benzonitrile . Substrates bearing two or more different unsaturated bonds were also investigated and transfer hydrogenation occurred with excellent chemoselectivity. Nano‐palladium catalyst in situ generated from Pd(OAc) 2 and HBPin extremely improved the TH efficiency. Furthermore, chemoselective anti‐Markovnikov hydrodeuteration of terminal aromatic olefins was achieved using D 2 O and HBPin via in situ HD generation and discrimination. magnified image" @default.
- W3044959356 created "2020-07-29" @default.
- W3044959356 creator A5007399488 @default.
- W3044959356 creator A5010755869 @default.
- W3044959356 creator A5029975178 @default.
- W3044959356 creator A5046479554 @default.
- W3044959356 creator A5066687710 @default.
- W3044959356 creator A5072829720 @default.
- W3044959356 creator A5086409755 @default.
- W3044959356 date "2020-08-07" @default.
- W3044959356 modified "2023-10-16" @default.
- W3044959356 title "Generalized Chemoselective Transfer Hydrogenation/Hydrodeuteration" @default.
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