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- W3045145848 abstract "The present work reports on an extensive study on structural, thermal, optical, and non-linear optical properties of zinc oxide modified phospho-tellurite glass as a function of doped samarium oxide content. By using the well-known Archimedes method, the densities of the samples have been estimated. The thermal properties of the glasses have been investigated by differential scanning calorimetry (DSC) measurements. The structural study of these glasses has been performed by X-ray diffraction (XRD) studies and Fourier transformation infrared (FTIR) analysis. The UV–visible spectra of these glasses have been studied, which indicates the indirect nature of the electronic transition. The optical band gap energy ( E opt ) and Urbach energy of these glass system have been estimated from their ultraviolet edges. Both parameters vary in a nonlinear fashion with the concentration of dopant samarium ion. The refractive index and polarizability of the glass samples have been estimated using the Dimitrov equation and Lorentz-Lorentz equation, respectively. A theoretical approach has been used to evaluate several parameters like non-linear refractive index, oxide ion polarizability, optical basicity, and the third-order optical susceptibility, which are correlated with the composition of the glasses. The obtained results reveal that small increment in samarium oxide content enhances the thermal stability of the glasses. • Samarium oxide doped mixed former phospho-tellurite glass has been synthesized. • Several optical parameters have been estimated from UV-VIS study. • Samples are amorphous, conducting and reflecting in nature. • Increase of samarium oxide content enhances the thermal stability, compactness and energy band gap of the glasses." @default.
- W3045145848 created "2020-07-29" @default.
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- W3045145848 date "2020-11-01" @default.
- W3045145848 modified "2023-10-02" @default.
- W3045145848 title "Influence of samarium content on structural, thermal, linear and non-linear optical properties of ZnO–TeO2–P2O5 glasses" @default.
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- W3045145848 doi "https://doi.org/10.1016/j.matchemphys.2020.123561" @default.
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