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- W3045311636 abstract "The control of the second coordination sphere in a coordination complex plays an important role in improving catalytic efficiency. Herein, we report a zinc porphyrin complex ZnPor8T with multiple flexible triazole units comprising the second coordination sphere, as an electrocatalyst for the highly selective electrochemical reduction of carbon dioxide (CO2) to carbon monoxide (CO). This electrocatalyst converted CO2 to CO with a Faradaic efficiency of 99 % and a current density of −6.2 mA cm−2 at −2.4 V vs. Fc/Fc+ in N,N-dimethylformamide using water as the proton source. Structure-function relationship studies were carried out on ZnPor8T analogs containing different numbers of triazole units and distinct triazole geometries; these unveiled that the triazole units function cooperatively to stabilize the CO2-catalyst adduct in order to facilitate intramolecular proton transfer. Our findings demonstrate that incorporating triazole units that function in a cooperative manner is a versatile strategy to enhance the activity of electrocatalytic CO2 conversion." @default.
- W3045311636 created "2020-07-29" @default.
- W3045311636 creator A5001451383 @default.
- W3045311636 creator A5003659941 @default.
- W3045311636 creator A5054570135 @default.
- W3045311636 creator A5064531873 @default.
- W3045311636 creator A5070044735 @default.
- W3045311636 creator A5090814775 @default.
- W3045311636 date "2020-11-16" @default.
- W3045311636 modified "2023-09-26" @default.
- W3045311636 title "Enhanced Electrocatalytic Activity of a Zinc Porphyrin for CO <sub>2</sub> Reduction: Cooperative Effects of Triazole Units in the Second Coordination Sphere" @default.
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