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- W3045469067 endingPage "3643" @default.
- W3045469067 startingPage "3635" @default.
- W3045469067 abstract "Abstract We have developed a palladium‐catalyzed cross‐coupling reaction of isocyanides with α‐diazoacetates to form active ketenimines and following a 1,4‐diazabicyclo[2.2.2]octane (DABCO) catalyzed aza‐Mannich type reaction with various 2‐mercaptoimidazoles for the synthesis of 1,3‐bis(β‐aminoacrylate)‐substituted 2‐mercaptoimidazole derivatives with structural diversity. In addition, the use of 1 H ‐benzo[ d ]imidazol‐2‐ol as the reaction partner also allowed the formation of 1,3‐bis(β‐aminoacrylate)‐substituted 2‐benzimidazolinone derivatives with moderate yields (34–52%). In the aza‐Mannich reaction, the regioselective N ‐attack rather than S ‐attack or O ‐attack at the electrophilic central carbon of ketenimines was observed. This tandem sequence is efficient since two C=C and two C−N bonds are consecutively created in one‐pot. magnified image" @default.
- W3045469067 created "2020-07-29" @default.
- W3045469067 creator A5007916931 @default.
- W3045469067 creator A5014355948 @default.
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- W3045469067 creator A5029563290 @default.
- W3045469067 creator A5060474327 @default.
- W3045469067 creator A5075752479 @default.
- W3045469067 date "2020-07-31" @default.
- W3045469067 modified "2023-10-02" @default.
- W3045469067 title "One‐Pot Tandem Protocol for the Synthesis of 1,3‐Bis(β‐aminoacrylate)‐Substituted 2‐Mercaptoimidazole Scaffolds" @default.
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