FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3045476082> ?p ?o ?g. }

• W3045476082 endingPage "3360" @default.
• W3045476082 startingPage "3353" @default.
• W3045476082 abstract "Abstract Doping boron (B) atoms into poly(ethylene glycol) (PEG)‐based solid polymer electrolytes (B‐PEG) is believed to be an attractive method to increase the lithium‐ion transference number ( ) because of the interaction between the electropositive B atoms and the anions of lithium salts. However, this effect can be largely impeded by the interaction between B and the electronegative ether oxygen atoms in the attached PEG molecular chains, which is referred to as a shielding effect. Enlarging the distance between the center B atoms and the electronegative ether oxygens is believed to be an effective way to reduce such shielding effect. In this work, different number of siloxane spacing groups (Si x ) are introduced in between the B atom and ether oxygen in the B‐PEG macromolecules (B‐Si x ‐PEGs x =0,1,3,5). As the siloxane oxygen has less electronegativity to ether oxygen, the shielding effects should be weakened and the ability of B atoms to trap the anions of lithium salt will increase. As the introduction of siloxane groups into the B‐Si x ‐PEGs polymer electrolytes will also reduce the neat contents of both B and PEG, which has the opposite effect on the whole ionic conductivities and values, both the ionic conductivities and values of B‐Si x ‐PEGs electrolytes first increase then decrease along with x increases from 0 to 5 when the [Li + ]:[EO] mole ratio is fixed at 1 : 10. The peak value exists at x =1. Meanwhile, both the mobilities of Li + ions (confirmed via 7 Li nuclear magnetic resonance (NMR) results) and bis(trifluoromethane) sulfonimide (TFSI − ) anions (confirmed from Raman spectra analysis) get their maximum values when x =1. However, if both the concentrations of TFSI − and B atoms in B‐Si x ‐PEGs electrolytes are taken into consideration, the normalized diffusion coefficient of TFSI − anions obtained by molecular dynamic (MD) simulation decrease monotonically when x increases from 0 to 5. As the diffusion coefficient of TFSI − anions is determined by the interaction probability and strength of TFSI − and B atoms; these results confirm that the interaction between the B atoms and TFSI − anions increase with x . Namely, the deshielding effects of siloxane spacing groups on B atoms increase along with the increase of x in the B‐Si x ‐PEGs polymer electrolytes, while it levels off when x exceeds 3." @default.
• W3045476082 created "2020-07-29" @default.
• W3045476082 creator A5012131084 @default.
• W3045476082 creator A5026029714 @default.
• W3045476082 creator A5029462231 @default.
• W3045476082 creator A5042848426 @default.
• W3045476082 creator A5075415907 @default.
• W3045476082 creator A5080683222 @default.
• W3045476082 date "2020-08-03" @default.
• W3045476082 modified "2023-10-17" @default.
• W3045476082 title "Mitigating the Shielding Effect of Ether Oxygen in Poly(ethylene glycol) on Boron Atoms in Boron‐Doped Poly(ethylene glycol) Hybrid Polymer Electrolyte by Introducing Siloxane Spacers" @default.
• W3045476082 cites W1669766884 @default.
• W3045476082 cites W1932772245 @default.
• W3045476082 cites W1972123750 @default.
• W3045476082 cites W1974350965 @default.
• W3045476082 cites W1980178040 @default.
• W3045476082 cites W2008192551 @default.
• W3045476082 cites W2016934659 @default.
• W3045476082 cites W2050745123 @default.
• W3045476082 cites W2052551423 @default.
• W3045476082 cites W2065619278 @default.
• W3045476082 cites W2084035119 @default.
• W3045476082 cites W2099698529 @default.
• W3045476082 cites W2110395021 @default.
• W3045476082 cites W2130583263 @default.
• W3045476082 cites W2156140248 @default.
• W3045476082 cites W2166798763 @default.
• W3045476082 cites W2169211003 @default.
• W3045476082 cites W2188623579 @default.
• W3045476082 cites W2272503324 @default.
• W3045476082 cites W2321168360 @default.
• W3045476082 cites W2326478613 @default.
• W3045476082 cites W2403935603 @default.
• W3045476082 cites W2438066852 @default.
• W3045476082 cites W2460531786 @default.
• W3045476082 cites W2529522174 @default.
• W3045476082 cites W2543741884 @default.
• W3045476082 cites W2545330157 @default.
• W3045476082 cites W2579501709 @default.
• W3045476082 cites W2587767928 @default.
• W3045476082 cites W2623355280 @default.
• W3045476082 cites W2752584414 @default.
• W3045476082 cites W2759937707 @default.
• W3045476082 cites W2766466307 @default.
• W3045476082 cites W2790755910 @default.
• W3045476082 cites W2884856122 @default.
• W3045476082 cites W2902441058 @default.
• W3045476082 cites W2920977994 @default.
• W3045476082 cites W2928784998 @default.
• W3045476082 cites W2932478038 @default.
• W3045476082 cites W2948650589 @default.
• W3045476082 cites W2955096609 @default.
• W3045476082 cites W2963299746 @default.
• W3045476082 cites W2997464980 @default.
• W3045476082 cites W570051822 @default.
• W3045476082 doi "https://doi.org/10.1002/celc.202000784" @default.
• W3045476082 hasPublicationYear "2020" @default.
• W3045476082 type Work @default.
• W3045476082 sameAs 3045476082 @default.
• W3045476082 citedByCount "1" @default.
• W3045476082 countsByYear W30454760822021 @default.
• W3045476082 crossrefType "journal-article" @default.
• W3045476082 hasAuthorship W3045476082A5012131084 @default.
• W3045476082 hasAuthorship W3045476082A5026029714 @default.
• W3045476082 hasAuthorship W3045476082A5029462231 @default.
• W3045476082 hasAuthorship W3045476082A5042848426 @default.
• W3045476082 hasAuthorship W3045476082A5075415907 @default.
• W3045476082 hasAuthorship W3045476082A5080683222 @default.
• W3045476082 hasConcept C134018914 @default.
• W3045476082 hasConcept C145148216 @default.
• W3045476082 hasConcept C147789679 @default.
• W3045476082 hasConcept C17525397 @default.
• W3045476082 hasConcept C177293861 @default.
• W3045476082 hasConcept C178790620 @default.
• W3045476082 hasConcept C179104552 @default.
• W3045476082 hasConcept C185592680 @default.
• W3045476082 hasConcept C188027245 @default.
• W3045476082 hasConcept C192562407 @default.
• W3045476082 hasConcept C2182769 @default.
• W3045476082 hasConcept C2776139660 @default.
• W3045476082 hasConcept C2777516009 @default.
• W3045476082 hasConcept C2778541603 @default.
• W3045476082 hasConcept C2780407432 @default.
• W3045476082 hasConcept C501308230 @default.
• W3045476082 hasConcept C521977710 @default.
• W3045476082 hasConcept C540031477 @default.
• W3045476082 hasConcept C68801617 @default.
• W3045476082 hasConcept C71924100 @default.
• W3045476082 hasConceptScore W3045476082C134018914 @default.
• W3045476082 hasConceptScore W3045476082C145148216 @default.
• W3045476082 hasConceptScore W3045476082C147789679 @default.
• W3045476082 hasConceptScore W3045476082C17525397 @default.
• W3045476082 hasConceptScore W3045476082C177293861 @default.
• W3045476082 hasConceptScore W3045476082C178790620 @default.
• W3045476082 hasConceptScore W3045476082C179104552 @default.
• W3045476082 hasConceptScore W3045476082C185592680 @default.
• W3045476082 hasConceptScore W3045476082C188027245 @default.
• W3045476082 hasConceptScore W3045476082C192562407 @default.

• next