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- W3045493044 abstract "Abstract Glycol‐mediated facile solvothermal process for synthesis of mesoporous cobalt ferrite (CoFe 2 O 4 ) nanoparticles (NPs) is reported. The structure, surface functionalization and morphology of the prepared sample are characterized by X‐ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and field emission scanning electron microscope (FESEM). The role of the electrolyte on the charge‐storage performance of the CoFe 2 O 4 NPs is investigated in detail by performing cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), electrochemical impedance spectroscopy (EIS) and cyclic stability tests in neutral (3M Na 2 SO 4 ) and alkaline (3M KOH) aqueous electrolytes. The electrochemical activity of inverse spinel CoFe 2 O 4 can be tuned with the electrolytes. It possesses specific capacitance ( C sp ) of 477 and 176 F/g in alkaline and neutral aqueous media respectively at a scan rate of 2 mV/s. The sample shows better performance in KOH electrolyte because of the smaller size of solvated ions whereas possesses better rate capability in the neutral electrolyte. Significant Coulombic efficiency of 97% is observed in alkaline medium with a rise in C sp upto 5,000 cycles, which remains constant until 10,000 cycles." @default.
- W3045493044 created "2020-08-03" @default.
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- W3045493044 date "2020-07-28" @default.
- W3045493044 modified "2023-10-16" @default.
- W3045493044 title "Effect of aqueous electrolytes on the supercapacitive performance of glycol‐mediated CoFe <sub>2</sub> O <sub>4</sub> nanoparticles" @default.
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- W3045493044 doi "https://doi.org/10.1002/apj.2548" @default.
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