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• W3045531036 abstract "Red emitting phosphors of Mn4+ doped fluorides are in high demand because the high color purities of phosphors make them potentially useful white light-emitting diodes (WLEDs) as backlights of electronic devices. We herein report an efficient red emitting phosphor KRbGeF6 : Mn4+ (KRGF : Mn) that was prepared by an in situ one-pot ion-exchange method at room temperature without organic solvents or HF. Homogenous mixtures of the starting materials with a stoichiometric KRGF : Mn ratio were partly dissolved in various acid solutions, and [MnF6]2- and [GeF6]2- successively underwent ion exchange under stirring. More importantly, in situ recrystallization of KRGF : Mn occurred simultaneously in solution with water as a solvent. Evidently, the formation of stable KRGF : Mn crystals propels the processes of dissolution and ion exchange. We also investigated the effect of inorganic acids on the resultant phases and photoluminescence properties of KRGF : Mn. The red phosphor KRGF : Mn prepared in HCl solution shows the highest luminescence intensity with an yield of 80%." @default.
• W3045531036 created "2020-08-03" @default.
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• W3045531036 date "2020-01-01" @default.
• W3045531036 modified "2023-09-23" @default.
• W3045531036 title "<i>In situ</i> organic solvent-free synthesis of a novel red emitting Mn⁴⁺ doped KRbGeF₆ phosphor at the room temperature" @default.
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• W3045531036 doi "https://doi.org/10.1039/d0dt02521f" @default.
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