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- W3045584692 abstract "Abstract The development of air stable solid chiral catalysts for asymmetric hydrogenation is very attractive for the large‐scale production of chiral compounds. Herein, we reported the synthesis of an ordered macroporous poly(ionic liquid) catalyst integrated with VDPEN‐RuOTf as air stable chiral catalyst for asymmetric hydrogenation of quinoline derivatives. Under ambient conditions, the solid catalyst afforded 97% conversion with 90% ee in the asymmetric hydrogenation of 2‐methylquinoline in water. It was found that the activity and enantioselectivity of poly(ionic liquid) catalyst decreases with surface hydrophobicity increasing, suggesting the important role of surface hydrophilicity in obtaining high activity and enantioselectivity in water. Control experiment suggests that water promotes the anti‐air stability of the poly(ionic liquid) catalyst. The combination of poly(ionic liquid) catalyst and water may provide a new approach for designing heterogeneous chiral catalyst with anti‐air stability." @default.
- W3045584692 created "2020-08-03" @default.
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- W3045584692 date "2020-07-28" @default.
- W3045584692 modified "2023-10-15" @default.
- W3045584692 title "Water‐Promoted Heterogeneous Asymmetric Hydrogenation of Quinolines over Ordered Macroporous Poly(ionic liquid) Catalyst" @default.
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- W3045584692 doi "https://doi.org/10.1002/ajoc.202000323" @default.
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