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• W3045684269 abstract "Abstract A metal‐free aryl amination reaction of aryl halides and amino acids; with the amino acid serving as the nucleophilic aminating agent, is reported. The reaction was achieved by the condensation of various aryl halides 1 with cyclic and acyclic amino acids 2 , in the presence of a cheap and readily available base, potassium carbonate, in refluxing ethanol/water solution (1 : 1) for 3 h, under simple operating conditions. The products, N ‐( p ‐substituted phenyl)‐amino‐2‐carboxylic acids 3–12 , were obtained in isolated yields of 25–90% and characterized by IR, 1 H‐ and 13 C‐NMR spectroscopy and high‐resolution mass spectrometry. These arylated amino acids are vital synthons and precursors to many compounds of physiological importance." @default.
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• W3045684269 date "2020-07-27" @default.
• W3045684269 modified "2023-10-14" @default.
• W3045684269 title "Transition Metal‐Free, Base‐Induced Arylation of Amino Acids: Synthesis of <i>N</i> ‐( <i>para</i> ‐Substituted phenyl)amino‐2‐carboxylic acids" @default.
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• W3045684269 doi "https://doi.org/10.1002/slct.202002446" @default.
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