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• W3045700993 endingPage "101076" @default.
• W3045700993 startingPage "101076" @default.
• W3045700993 abstract "Abstract Adsorption is very economical and environmentally friendly method that is commonly accepted as a promising technique for the removal of heavy metals. In this study a fungal-extract-based (FE-CB) bio-nanosorbent was prepared and used as an efficient biosorbent for the removal of heavy metals, namely Cu(II) and Ni(II), from aqueous solutions. FE-CB was characterized by scanning electron microscope, Brunauer–Emmett–Teller surface area and porosity analyzer, Fourier transform infrared, x-ray diffraction, differential scanning calorimeter, thermalgravimetric analysis and zeta potential. The Brunauer–Emmett–Teller surface area, pore volume and average pore diameter of FE-CB were 7.43 m2/g, 0.060 cm3/g, and 2.82 nm, respectively. The adsorbtion properties of FE-CB onto both Cu(II) and Ni(II) were investigated in terms of biosorbent dosage, temperature, initial concentration of Cu(II) and Ni(II) ions, pH and contact time in the batch experiments. The dependence of the biosorption mechanism on pH was revealed and the optimum pH was determined as 6 for Ni(II) and 5 for Cu(II). The Langmuir and Freundlich isothermal models and the kinetic Pseudo-first-order and Pseudo-second-order kinetic models were used to describe the adsorption performance of FE-CB. The activation energy was calculated by pseudo-second-order rate constants. In addition, thermodynamic parameters, standard Gibbs free energy, standard enthalpy and standard entropy were analyzed using the (Van’t Hoff equation). The biosorption process was found to be spontaneous, favorable and endothermic." @default.
• W3045700993 created "2020-08-03" @default.
• W3045700993 creator A5007028443 @default.
• W3045700993 creator A5051315534 @default.
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• W3045700993 date "2020-11-01" @default.
• W3045700993 modified "2023-09-23" @default.
• W3045700993 title "Kinetic and isotherm investigation into the removal of heavy metals using a fungal-extract-based bio-nanosorbent" @default.
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• W3045700993 doi "https://doi.org/10.1016/j.eti.2020.101076" @default.
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