Matches in SemOpenAlex for { <https://semopenalex.org/work/W3045814391> ?p ?o ?g. }
- W3045814391 endingPage "8695" @default.
- W3045814391 startingPage "8691" @default.
- W3045814391 abstract "Abstract The treatment of [M(L OEt )(N)Cl 2 ] (L OEt − =[Co(η 5 ‐C 5 H 5 ){P(O)(OEt) 2 } 3 ] − ) with the Pt(II) bis(cyclometalated) complex [Pt(C N CBu)(DMSO)] (H 2 C N CBu=2,6‐di(4‐ tert ‐butylphenyl)pyridine; DMSO=dimethylsulfoxide) afforded the heterotrinuclear nitrido complexes [L OEt Cl 2 M(μ‐N)Pt(C N CBu)] (M=Ru ( 1‐Ru ), Os ( 1‐Os )). The Pt−N(nitrido) (1.821(5) Å) and Ru−N (1.673(5) Å) distances in 1‐Ru are consistent with the Ru=N=Pt bonding description. The Pt−N(nitrido) distance in 1‐Os (1.859(7) Å) is longer than that in 1‐Ru , suggesting the π interaction between Pt(II) and Os≡N is weaker than that for the Ru counterpart. Oxidation of 1‐Ru with PhICl 2 afforded the Pt(IV) dichloride complex [L OEt Cl 2 Ru(μ‐N)Pt(C N CBu)Cl 2 ] ( 2 ) that has a longer Pt−N distance (1.893(3) Å) than that in 1‐Ru , indicating the weakening of the Pt−N(Ru) π bonding upon oxidation of Pt(II) to Pt(IV). Treatment of [Pt(C N CBu)(DMSO)] with [ n Bu 4 N][Ru(N)Cl 4 ] in tetrahydrofuran (THF) afforded [ n Bu 4 N][(THF)Cl 4 Ru(μ‐N)Pt(C N CBu)] ( 3 ), which reacted with K[N(Ph 2 PS) 2 ] and K[N (i Pr 2 PO) 2 ] to yield [Cl{N(Ph 2 PS)2} 2 Ru(μ‐N)Pt(C N CBu)] ( 4 ) and [ n Bu 4 N][Cl 3 {N( i Pr 2 PO) 2 }Ru(μ‐N)Pt(C N CBu)] ( 5 ), respectively. The short Pt−N(nitrido) distances in 3 (1.816(5) Å) and 4 (1.809(2) Å) are indicative of Pt=N double bond character." @default.
- W3045814391 created "2020-08-03" @default.
- W3045814391 creator A5001320568 @default.
- W3045814391 creator A5003861735 @default.
- W3045814391 creator A5023180659 @default.
- W3045814391 creator A5033856965 @default.
- W3045814391 creator A5042322544 @default.
- W3045814391 creator A5088557049 @default.
- W3045814391 date "2020-07-27" @default.
- W3045814391 modified "2023-10-16" @default.
- W3045814391 title "Synthesis and Reactivity of Heterotrinuclear Platinum Cyclometalated Complexes Containing Bridging Nitrido Ligands" @default.
- W3045814391 cites W1487697148 @default.
- W3045814391 cites W1971979932 @default.
- W3045814391 cites W1984032555 @default.
- W3045814391 cites W1991056901 @default.
- W3045814391 cites W1998004605 @default.
- W3045814391 cites W2009518314 @default.
- W3045814391 cites W2015620077 @default.
- W3045814391 cites W2022331086 @default.
- W3045814391 cites W2024869810 @default.
- W3045814391 cites W2036823723 @default.
- W3045814391 cites W2040473668 @default.
- W3045814391 cites W2045397008 @default.
- W3045814391 cites W2047890653 @default.
- W3045814391 cites W2050474073 @default.
- W3045814391 cites W2053155756 @default.
- W3045814391 cites W2057688830 @default.
- W3045814391 cites W2069700736 @default.
- W3045814391 cites W2072329606 @default.
- W3045814391 cites W2074343777 @default.
- W3045814391 cites W2077301059 @default.
- W3045814391 cites W2089730316 @default.
- W3045814391 cites W2107336468 @default.
- W3045814391 cites W2143081356 @default.
- W3045814391 cites W2170743197 @default.
- W3045814391 cites W2278967167 @default.
- W3045814391 cites W2293505006 @default.
- W3045814391 cites W2329373807 @default.
- W3045814391 cites W2433494418 @default.
- W3045814391 cites W2536464040 @default.
- W3045814391 cites W2606278280 @default.
- W3045814391 cites W2622100622 @default.
- W3045814391 cites W2744716218 @default.
- W3045814391 cites W2788383981 @default.
- W3045814391 cites W2898682964 @default.
- W3045814391 cites W2919590149 @default.
- W3045814391 cites W3008617201 @default.
- W3045814391 cites W3013610388 @default.
- W3045814391 cites W2120407245 @default.
- W3045814391 doi "https://doi.org/10.1002/slct.202002319" @default.
- W3045814391 hasPublicationYear "2020" @default.
- W3045814391 type Work @default.
- W3045814391 sameAs 3045814391 @default.
- W3045814391 citedByCount "0" @default.
- W3045814391 crossrefType "journal-article" @default.
- W3045814391 hasAuthorship W3045814391A5001320568 @default.
- W3045814391 hasAuthorship W3045814391A5003861735 @default.
- W3045814391 hasAuthorship W3045814391A5023180659 @default.
- W3045814391 hasAuthorship W3045814391A5033856965 @default.
- W3045814391 hasAuthorship W3045814391A5042322544 @default.
- W3045814391 hasAuthorship W3045814391A5088557049 @default.
- W3045814391 hasConcept C134121241 @default.
- W3045814391 hasConcept C142724271 @default.
- W3045814391 hasConcept C155647269 @default.
- W3045814391 hasConcept C161790260 @default.
- W3045814391 hasConcept C178790620 @default.
- W3045814391 hasConcept C185592680 @default.
- W3045814391 hasConcept C191897082 @default.
- W3045814391 hasConcept C192562407 @default.
- W3045814391 hasConcept C204787440 @default.
- W3045814391 hasConcept C2776701986 @default.
- W3045814391 hasConcept C2776910235 @default.
- W3045814391 hasConcept C2779485729 @default.
- W3045814391 hasConcept C2780471494 @default.
- W3045814391 hasConcept C518104683 @default.
- W3045814391 hasConcept C555196967 @default.
- W3045814391 hasConcept C71240020 @default.
- W3045814391 hasConcept C71924100 @default.
- W3045814391 hasConceptScore W3045814391C134121241 @default.
- W3045814391 hasConceptScore W3045814391C142724271 @default.
- W3045814391 hasConceptScore W3045814391C155647269 @default.
- W3045814391 hasConceptScore W3045814391C161790260 @default.
- W3045814391 hasConceptScore W3045814391C178790620 @default.
- W3045814391 hasConceptScore W3045814391C185592680 @default.
- W3045814391 hasConceptScore W3045814391C191897082 @default.
- W3045814391 hasConceptScore W3045814391C192562407 @default.
- W3045814391 hasConceptScore W3045814391C204787440 @default.
- W3045814391 hasConceptScore W3045814391C2776701986 @default.
- W3045814391 hasConceptScore W3045814391C2776910235 @default.
- W3045814391 hasConceptScore W3045814391C2779485729 @default.
- W3045814391 hasConceptScore W3045814391C2780471494 @default.
- W3045814391 hasConceptScore W3045814391C518104683 @default.
- W3045814391 hasConceptScore W3045814391C555196967 @default.
- W3045814391 hasConceptScore W3045814391C71240020 @default.
- W3045814391 hasConceptScore W3045814391C71924100 @default.
- W3045814391 hasIssue "28" @default.
- W3045814391 hasLocation W30458143911 @default.
- W3045814391 hasOpenAccess W3045814391 @default.