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- W3045953103 abstract "A new ytterbium copper antimonide, YbCu0.52(2)Sb, was synthesized from the Pb-flux reactions, and its crystal structure was determined by the single-crystal X-ray diffraction method. The compound crystallizes in the trigonal space groupR3¯m (No. 166), a = 4.4494(4) Å, c = 33.767(7) Å, which adopts the same structure as Ca0.61(1)Ce0.39(1)Ag0.60(1)Sb. The crystal structure of this compound can be rationalized as a combination of the YbCuSb and YbSb structures. Also, the formula can be written as a sum of these two components, [(Yb2+)(Cu+)(Sb3−)]0.52[(Yb3+)(Sb3−)]0.48. The magnetic susceptibility measurements indicated coexistence of Yb2+ and Yb3+ in the structure, which was further supported by the X-ray photoelectron spectroscopy. The temperature dependent resistivity measurements indicated the metallic nature of the material. Since the Yb-Cu-Sb system contains very limited member compounds, the discovery of this ternary YbCu0.52(2)Sb phase is important, which represents a completely new fashion in stabilizing the crystal structure." @default.
- W3045953103 created "2020-08-03" @default.
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- W3045953103 date "2020-12-01" @default.
- W3045953103 modified "2023-10-15" @default.
- W3045953103 title "YbCu0.52(2)Sb: Mixed-valent compound with a layered structure" @default.
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- W3045953103 doi "https://doi.org/10.1016/j.jallcom.2020.156551" @default.
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