FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3045962004> ?p ?o ?g. }

• W3045962004 endingPage "19632" @default.
• W3045962004 startingPage "19625" @default.
• W3045962004 abstract "Biocatalytic upgrading of biomass-derived 5-hydroxymethylfurfural (HMF) into high-value derivatives is of great significance in green chemistry. In this study, we disclosed the successful utilization of whole-cell Paraburkholderia azotifigens F18 for its switchable catalytic performance in the on-demand catalysis of HMF to different value-added derivatives, namely, selective reduction to 2,5-bis(hydroxymethyl)furan (BHMF) or oxidation to 5-hydroxymethyl-2-furancarboxylic acid (HMFCA). Based on the fine-tuning of biochemical properties, the biocatalyst can proceed an efficient hydrogenation reaction toward HMF with a good selectivity of 97.6% to yield the BHMF at 92.2%. Noteworthily, BHMF could be further oxidized to HMFCA and 2,5-furandicarboxylic acid (FDCA) by the whole cell. To realize the on-demand syntheses of HMFCA, the genes encoding HMF oxidoreductase/oxidase of whole-cell F18 were then deleted to prevent the further conversion of HMFCA to FDCA, which led to a 10-fold decrease of FDCA. Thus, an HMF conversion of 100% with an HMFCA yield of 98.3% was finally achieved by the engineered whole cell at a substrate concentration of 150 mM. Moreover, HMFCA synthesis was efficiently prepared with an excellent selectivity of 96.3% and a yield of 85.1% even at a high substrate concentration of up to 200 mM." @default.
• W3045962004 created "2020-08-03" @default.
• W3045962004 creator A5004349988 @default.
• W3045962004 creator A5007571603 @default.
• W3045962004 creator A5036356189 @default.
• W3045962004 creator A5041918327 @default.
• W3045962004 creator A5062283137 @default.
• W3045962004 creator A5068570479 @default.
• W3045962004 creator A5071897391 @default.
• W3045962004 creator A5074297726 @default.
• W3045962004 date "2020-07-27" @default.
• W3045962004 modified "2023-10-16" @default.
• W3045962004 title "Redox-Switchable Biocatalyst for Controllable Oxidation or Reduction of 5-Hydroxymethylfurfural into High-Value Derivatives" @default.
• W3045962004 cites W1551071168 @default.
• W3045962004 cites W1910551730 @default.
• W3045962004 cites W1968499092 @default.
• W3045962004 cites W1975617383 @default.
• W3045962004 cites W1987643155 @default.
• W3045962004 cites W1996230210 @default.
• W3045962004 cites W2002031010 @default.
• W3045962004 cites W2003244207 @default.
• W3045962004 cites W2004370186 @default.
• W3045962004 cites W2013366433 @default.
• W3045962004 cites W2016466394 @default.
• W3045962004 cites W2059810529 @default.
• W3045962004 cites W2060363933 @default.
• W3045962004 cites W2062862417 @default.
• W3045962004 cites W2092438050 @default.
• W3045962004 cites W2098703212 @default.
• W3045962004 cites W2102812055 @default.
• W3045962004 cites W2141949253 @default.
• W3045962004 cites W2156326383 @default.
• W3045962004 cites W2169801839 @default.
• W3045962004 cites W2316551736 @default.
• W3045962004 cites W2562309858 @default.
• W3045962004 cites W2562411955 @default.
• W3045962004 cites W2749179754 @default.
• W3045962004 cites W2750889807 @default.
• W3045962004 cites W2801389690 @default.
• W3045962004 cites W2803640131 @default.
• W3045962004 cites W2897353733 @default.
• W3045962004 cites W2920023654 @default.
• W3045962004 cites W4241524717 @default.
• W3045962004 doi "https://doi.org/10.1021/acsomega.0c02178" @default.
• W3045962004 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7424722" @default.
• W3045962004 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32803057" @default.
• W3045962004 hasPublicationYear "2020" @default.
• W3045962004 type Work @default.
• W3045962004 sameAs 3045962004 @default.
• W3045962004 citedByCount "14" @default.
• W3045962004 countsByYear W30459620042021 @default.
• W3045962004 countsByYear W30459620042022 @default.
• W3045962004 countsByYear W30459620042023 @default.
• W3045962004 crossrefType "journal-article" @default.
• W3045962004 hasAuthorship W3045962004A5004349988 @default.
• W3045962004 hasAuthorship W3045962004A5007571603 @default.
• W3045962004 hasAuthorship W3045962004A5036356189 @default.
• W3045962004 hasAuthorship W3045962004A5041918327 @default.
• W3045962004 hasAuthorship W3045962004A5062283137 @default.
• W3045962004 hasAuthorship W3045962004A5068570479 @default.
• W3045962004 hasAuthorship W3045962004A5071897391 @default.
• W3045962004 hasAuthorship W3045962004A5074297726 @default.
• W3045962004 hasBestOaLocation W30459620041 @default.
• W3045962004 hasConcept C111368507 @default.
• W3045962004 hasConcept C118792377 @default.
• W3045962004 hasConcept C127313418 @default.
• W3045962004 hasConcept C134121241 @default.
• W3045962004 hasConcept C161790260 @default.
• W3045962004 hasConcept C178790620 @default.
• W3045962004 hasConcept C185592680 @default.
• W3045962004 hasConcept C191503008 @default.
• W3045962004 hasConcept C191897082 @default.
• W3045962004 hasConcept C192562407 @default.
• W3045962004 hasConcept C21951064 @default.
• W3045962004 hasConcept C2777289219 @default.
• W3045962004 hasConcept C2778659115 @default.
• W3045962004 hasConcept C2780591741 @default.
• W3045962004 hasConcept C55904794 @default.
• W3045962004 hasConcept C65024703 @default.
• W3045962004 hasConceptScore W3045962004C111368507 @default.
• W3045962004 hasConceptScore W3045962004C118792377 @default.
• W3045962004 hasConceptScore W3045962004C127313418 @default.
• W3045962004 hasConceptScore W3045962004C134121241 @default.
• W3045962004 hasConceptScore W3045962004C161790260 @default.
• W3045962004 hasConceptScore W3045962004C178790620 @default.
• W3045962004 hasConceptScore W3045962004C185592680 @default.
• W3045962004 hasConceptScore W3045962004C191503008 @default.
• W3045962004 hasConceptScore W3045962004C191897082 @default.
• W3045962004 hasConceptScore W3045962004C192562407 @default.
• W3045962004 hasConceptScore W3045962004C21951064 @default.
• W3045962004 hasConceptScore W3045962004C2777289219 @default.
• W3045962004 hasConceptScore W3045962004C2778659115 @default.
• W3045962004 hasConceptScore W3045962004C2780591741 @default.
• W3045962004 hasConceptScore W3045962004C55904794 @default.
• W3045962004 hasConceptScore W3045962004C65024703 @default.
• W3045962004 hasFunder F4320321605 @default.
• W3045962004 hasFunder F4320322769 @default.
• W3045962004 hasIssue "31" @default.

• next