FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3045989683> ?p ?o ?g. }

• W3045989683 endingPage "109914" @default.
• W3045989683 startingPage "109914" @default.
• W3045989683 abstract "We present controlled de-cross-linking and detemplating for modifying the porosity and covalent structure of porous organic polymers. HC≡C-C6H4-CH=N-C6H4-N=CH-C6H4-C≡CH and HC≡C-C6H4-N=CH-C6H4-CH=N-C6H4-C≡CH type monomers (-C6H4- is meta- and para-phenylene) having two polymerizable ethynyl groups and two hydrolysable azomethine groups per molecule were copolymerized with 4,4-diethynylbiphenyl and tetrakis(4-ethynylphenyl)methane into porous polyacetylene-type hyper-cross-linked networks. Two types of cross-links were involved in cross-linking: hydrolysable Schiff-base-type cross-links and stable non-hydrolysable cross-links. Postpolymerization hydrolysis caused cleavage of the azomethine groups and release of phenylenediamine or diformylbenzene template segments from the Schiff-base-type cross-links. Although hydrolysis resulted in partial de-cross-linking, stable cross-links remaining in the networks prevented the collapse of the porous texture. Partial de-cross-linking led to an increase in the micropore diameter and, moreover, –HC=O or –NH2 groups were introduced into the networks in this way. Modified networks decorated with above groups acted as chemisorbents for trapping aldehydes or primary amines under formation of azomethine links between the network and adsorptive." @default.
• W3045989683 created "2020-08-03" @default.
• W3045989683 creator A5000885751 @default.
• W3045989683 creator A5007679070 @default.
• W3045989683 creator A5015269991 @default.
• W3045989683 creator A5046198631 @default.
• W3045989683 creator A5049014274 @default.
• W3045989683 creator A5050611545 @default.
• W3045989683 creator A5066957201 @default.
• W3045989683 date "2020-08-01" @default.
• W3045989683 modified "2023-09-30" @default.
• W3045989683 title "Microporous hyper-cross-linked polyacetylene networks: Covalent structure and texture modification by reversible Schiff-base chemistry" @default.
• W3045989683 cites W1909940713 @default.
• W3045989683 cites W1949855949 @default.
• W3045989683 cites W1966470510 @default.
• W3045989683 cites W1967148386 @default.
• W3045989683 cites W1978429607 @default.
• W3045989683 cites W1988206787 @default.
• W3045989683 cites W1992844372 @default.
• W3045989683 cites W2000547213 @default.
• W3045989683 cites W2001672090 @default.
• W3045989683 cites W2009467967 @default.
• W3045989683 cites W2009840678 @default.
• W3045989683 cites W2021681230 @default.
• W3045989683 cites W2027107962 @default.
• W3045989683 cites W2028845563 @default.
• W3045989683 cites W2034438428 @default.
• W3045989683 cites W2047307520 @default.
• W3045989683 cites W2052641095 @default.
• W3045989683 cites W2055663330 @default.
• W3045989683 cites W2058236705 @default.
• W3045989683 cites W2058491584 @default.
• W3045989683 cites W2063426798 @default.
• W3045989683 cites W2065148350 @default.
• W3045989683 cites W2075285544 @default.
• W3045989683 cites W2078967322 @default.
• W3045989683 cites W2079597154 @default.
• W3045989683 cites W2094382049 @default.
• W3045989683 cites W2112201117 @default.
• W3045989683 cites W2141980865 @default.
• W3045989683 cites W2169654026 @default.
• W3045989683 cites W2304216771 @default.
• W3045989683 cites W2314143529 @default.
• W3045989683 cites W2321248279 @default.
• W3045989683 cites W2327837350 @default.
• W3045989683 cites W2329518550 @default.
• W3045989683 cites W2335873243 @default.
• W3045989683 cites W2337183627 @default.
• W3045989683 cites W2338887012 @default.
• W3045989683 cites W2399610848 @default.
• W3045989683 cites W2414993757 @default.
• W3045989683 cites W2580988338 @default.
• W3045989683 cites W2586141782 @default.
• W3045989683 cites W2600201079 @default.
• W3045989683 cites W2605966263 @default.
• W3045989683 cites W2632615776 @default.
• W3045989683 cites W2765469772 @default.
• W3045989683 cites W2768988432 @default.
• W3045989683 cites W2769525042 @default.
• W3045989683 cites W2784641283 @default.
• W3045989683 cites W2794095287 @default.
• W3045989683 cites W2807275545 @default.
• W3045989683 cites W2810647336 @default.
• W3045989683 cites W2831389266 @default.
• W3045989683 cites W2886470290 @default.
• W3045989683 cites W2896749907 @default.
• W3045989683 cites W2902015819 @default.
• W3045989683 cites W2904527208 @default.
• W3045989683 cites W2917122645 @default.
• W3045989683 cites W2941816392 @default.
• W3045989683 cites W2944520790 @default.
• W3045989683 cites W2986649674 @default.
• W3045989683 cites W2993131193 @default.
• W3045989683 cites W2998087145 @default.
• W3045989683 cites W3003716272 @default.
• W3045989683 cites W3004175453 @default.
• W3045989683 cites W4238820738 @default.
• W3045989683 doi "https://doi.org/10.1016/j.eurpolymj.2020.109914" @default.
• W3045989683 hasPublicationYear "2020" @default.
• W3045989683 type Work @default.
• W3045989683 sameAs 3045989683 @default.
• W3045989683 citedByCount "3" @default.
• W3045989683 countsByYear W30459896832021 @default.
• W3045989683 countsByYear W30459896832023 @default.
• W3045989683 crossrefType "journal-article" @default.
• W3045989683 hasAuthorship W3045989683A5000885751 @default.
• W3045989683 hasAuthorship W3045989683A5007679070 @default.
• W3045989683 hasAuthorship W3045989683A5015269991 @default.
• W3045989683 hasAuthorship W3045989683A5046198631 @default.
• W3045989683 hasAuthorship W3045989683A5049014274 @default.
• W3045989683 hasAuthorship W3045989683A5050611545 @default.
• W3045989683 hasAuthorship W3045989683A5066957201 @default.
• W3045989683 hasConcept C166940927 @default.
• W3045989683 hasConcept C178790620 @default.
• W3045989683 hasConcept C180577832 @default.
• W3045989683 hasConcept C185592680 @default.
• W3045989683 hasConcept C188027245 @default.
• W3045989683 hasConcept C2776428424 @default.

• next