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- W3046021471 abstract "Porous metal complexes enable single-crystal X-ray crystallographic observation of included guests or reaction intermediates through simple soaking with the guests/substrates. Previous studies on this technique have often encountered difficulties in the observation of chiral structures because the host frameworks had no chirality. We synthesized a new metal-peptide porous complex through a folding-and-assembly strategy and utilized the chiral pore for trapping chiral guests. Chiral alcohols and ketones were successfully included within the pore. Crystallographic analyses clearly revealed not only their chemical structures but also chiral transformation events within the pore such as fixed conformations or an unstable hemiacetal formation." @default.
- W3046021471 created "2020-08-03" @default.
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- W3046021471 date "2020-09-01" @default.
- W3046021471 modified "2023-10-14" @default.
- W3046021471 title "X‐ray Crystallographic Observation of Chiral Transformations within a Metal–Peptide Pore" @default.
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- W3046021471 doi "https://doi.org/10.1002/anie.202007731" @default.
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