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- W3046374436 abstract "Abstract The selective formal insertion (homologation) of a carbon unit bridging the two trifluoroacetamidoyl chlorides (TFAICs) units is reported. The tactic is levered on a highly chemoselective homologation–metalation–acyl nucleophilic substitution sequence which precisely enables to assemble novel trifluoromethylated β‐diketiminates within a single synthetic operation. Unlike previous homologations conducted with LiCH 2 Cl furnishing aziridines, herein we exploit the unique capability of iodomethyllithium to act contemporaneously as a C1 source (homologating effect) and metalating agent. The mechanistic rationale grounded on experimental evidences supports the hypothesized proposal and, the structural analysis gathers key aspects of this class of valuable ligands in catalysis." @default.
- W3046374436 created "2020-08-07" @default.
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- W3046374436 date "2020-09-09" @default.
- W3046374436 modified "2023-10-16" @default.
- W3046374436 title "Halogen‐Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis‐Trifluoromethyl‐β‐Diketiminates and the Dual Role of LiCH<sub>2</sub>I" @default.
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- W3046374436 doi "https://doi.org/10.1002/anie.202007954" @default.
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