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- W3046504845 endingPage "122783" @default.
- W3046504845 startingPage "122783" @default.
- W3046504845 abstract "A series of networks is introduced with systematically varied network heterogeneity and high overall values of average glass transition temperature (Tg), based on polymerization of rigid acrylate and aromatic thiol monomers. The curing behavior, chain dynamics, and microstructure of these networks were investigated through a combination of dynamic mechanical analysis and infrared spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, and x-ray scattering, respectively. The maximum Tg achieved during cure can be related to the breadth of the mechanical loss tangent, as others have previously suggested, as well as the temperature dependence of the chain dynamics in the network as monitored by 1H NMR. In addition, the microstructures of the networks are characterized by periodic, fractal microgels with characteristic length scales of ca. 20–40 nm. Intriguingly, this structural motif persists in the more homogeneous networks exhibiting comparatively narrow glass transitions and chain dynamics, indicating that dynamically homogeneous networks can still exhibit significant compositional heterogeneity at the mesoscale." @default.
- W3046504845 created "2020-08-07" @default.
- W3046504845 creator A5012327587 @default.
- W3046504845 creator A5063942792 @default.
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- W3046504845 date "2020-09-01" @default.
- W3046504845 modified "2023-10-06" @default.
- W3046504845 title "Curing behavior, chain dynamics, and microstructure of high Tg thiol-acrylate networks with systematically varied network heterogeneity" @default.
- W3046504845 cites W1191887444 @default.
- W3046504845 cites W1968818436 @default.
- W3046504845 cites W1970404736 @default.
- W3046504845 cites W1974148355 @default.
- W3046504845 cites W1974496199 @default.
- W3046504845 cites W1974643323 @default.
- W3046504845 cites W1978872559 @default.
- W3046504845 cites W1980372128 @default.
- W3046504845 cites W1982052532 @default.
- W3046504845 cites W1982252409 @default.
- W3046504845 cites W1982754043 @default.
- W3046504845 cites W1982768544 @default.
- W3046504845 cites W1983865998 @default.
- W3046504845 cites W1989149290 @default.
- W3046504845 cites W1994816738 @default.
- W3046504845 cites W1996309569 @default.
- W3046504845 cites W2002956944 @default.
- W3046504845 cites W2004876150 @default.
- W3046504845 cites W2011743692 @default.
- W3046504845 cites W2013726917 @default.
- W3046504845 cites W2017928816 @default.
- W3046504845 cites W2018621610 @default.
- W3046504845 cites W2021531659 @default.
- W3046504845 cites W2027232223 @default.
- W3046504845 cites W2031250486 @default.
- W3046504845 cites W2036823634 @default.
- W3046504845 cites W2037869307 @default.
- W3046504845 cites W2043252472 @default.
- W3046504845 cites W2047055771 @default.
- W3046504845 cites W2051621895 @default.
- W3046504845 cites W2057009283 @default.
- W3046504845 cites W2057314363 @default.
- W3046504845 cites W2062051207 @default.
- W3046504845 cites W2064346669 @default.
- W3046504845 cites W2072560026 @default.
- W3046504845 cites W2081576516 @default.
- W3046504845 cites W2082814755 @default.
- W3046504845 cites W2085561789 @default.
- W3046504845 cites W2088050279 @default.
- W3046504845 cites W2088640386 @default.
- W3046504845 cites W2088767435 @default.
- W3046504845 cites W2093805114 @default.
- W3046504845 cites W2104676217 @default.
- W3046504845 cites W2107613607 @default.
- W3046504845 cites W2112841392 @default.
- W3046504845 cites W2114721114 @default.
- W3046504845 cites W2122801376 @default.
- W3046504845 cites W2135242737 @default.
- W3046504845 cites W2138270017 @default.
- W3046504845 cites W2143623010 @default.
- W3046504845 cites W2153654441 @default.
- W3046504845 cites W2156291417 @default.
- W3046504845 cites W2163522063 @default.
- W3046504845 cites W2164664188 @default.
- W3046504845 cites W2166027129 @default.
- W3046504845 cites W2167066199 @default.
- W3046504845 cites W2173993448 @default.
- W3046504845 cites W2288825269 @default.
- W3046504845 cites W2300893921 @default.
- W3046504845 cites W2321248279 @default.
- W3046504845 cites W2323157840 @default.
- W3046504845 cites W2326833210 @default.
- W3046504845 cites W2327642271 @default.
- W3046504845 cites W2332324726 @default.
- W3046504845 cites W2334702618 @default.
- W3046504845 cites W2372541428 @default.
- W3046504845 cites W2479010031 @default.
- W3046504845 cites W2511842231 @default.
- W3046504845 cites W2520561070 @default.
- W3046504845 cites W2552610471 @default.
- W3046504845 cites W2561939592 @default.
- W3046504845 cites W2580670600 @default.
- W3046504845 cites W2606925959 @default.
- W3046504845 cites W2606974400 @default.
- W3046504845 cites W2620269590 @default.
- W3046504845 cites W2621780002 @default.
- W3046504845 cites W2734817487 @default.
- W3046504845 cites W2750415276 @default.
- W3046504845 cites W2760759007 @default.
- W3046504845 cites W2765633115 @default.
- W3046504845 cites W2767532140 @default.
- W3046504845 cites W2773929148 @default.
- W3046504845 cites W2777368240 @default.
- W3046504845 cites W2789526112 @default.