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- W3046880059 abstract "The aim of the paper was to investigate the ability of an eco-friendly luminescent xerogel prepared by chitosan crosslinking with a phenothiazine luminogen to detect and remove heavy metals. Its ability to give a divergent morphological and optical response towards fifteen environmental relevant metals was investigated by naked eye and UV lamp, fluorescence spectroscopy and scanning electron microscopy. A distinct response was noted for mercury, consisting in the transformation of the xerogel into a rubber-like material accompanied by the red shifting of the color of emitted light from yellow-green to greenish-yellow domain. The particularities of the metals anchoring into the xerogel were analyzed by FTIR spectroscopy and X-ray diffraction. The morphological changes and the metal uptake were analyzed by SEM-EDAX, swelling and gravimetric methods. It was concluded that mercury has a superior affinity towards this heteroatoms rich system, leading to a secondary crosslinking. This directed a great absorption capacity of 1673 mg/g and a specific morphological response for mercury ion concentrations up to 0.001 ppm." @default.
- W3046880059 created "2020-08-07" @default.
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- W3046880059 date "2020-11-01" @default.
- W3046880059 modified "2023-10-18" @default.
- W3046880059 title "Phenothiazine-chitosan based eco-adsorbents: A special design for mercury removal and fast naked eye detection" @default.
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- W3046880059 doi "https://doi.org/10.1016/j.ijbiomac.2020.07.232" @default.
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