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- W3047196252 abstract "The first enantioselective hydrogenation of terpyridine-type N-heteroarenes has been successfully developed by using Ru(diamine) complexes as catalysts, providing partially reduced chiral pyridine-amine-type products in high yield (up to 93%) with excellent diastereo- and enantioselectivity (up to 94:6 dl/meso, > 99% ee). These pyridine-amine-type compounds can be served as a new class of chiral multidentate nitrogen-donor ligands, which were successfully applied to the Cu-catalyzed asymmetric Friedel-Crafts alkylation reaction of indoles with nitroalkenes." @default.
- W3047196252 created "2020-08-10" @default.
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- W3047196252 date "2020-08-03" @default.
- W3047196252 modified "2023-10-03" @default.
- W3047196252 title "Asymmetric Ruthenium-Catalyzed Hydrogenation of Terpyridine-Type <i>N</i>-Heteroarenes: Direct Access to Chiral Tridentate Nitrogen Ligands" @default.
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- W3047196252 doi "https://doi.org/10.1021/acs.orglett.0c02268" @default.
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