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- W3047248968 abstract "Abstract Remote difunctionalization of unactivated alkenes is challenging but a highly attractive tactic to install two functional groups across long distances. Reported herein is the first remote difunctionalization of alkenes with CO 2 . This visible‐light photoredox catalysis strategy provides a facile method to synthesize a series of carboxylic acids bearing valuable fluorine‐ or phosphorus‐containing functional groups. Moreover, this versatile protocol shows mild reaction conditions, broad substrate scope, and good functional‐group tolerance. Based on DFT calculations, a radical adds to an unactivated alkene to smoothly form a new carbon radical, followed by a 1,5‐hydrogen atom‐transfer process, the rate‐limiting step, generating a more stable benzylic radical. The reduction of the benzylic radicals by an Ir II species generates the corresponding benzylic carbanions as the key intermediates, which further undergo nucleophilic attack with CO 2 to generate carboxylates." @default.
- W3047248968 created "2020-08-10" @default.
- W3047248968 creator A5007556274 @default.
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- W3047248968 creator A5016358859 @default.
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- W3047248968 creator A5054829836 @default.
- W3047248968 creator A5059599037 @default.
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- W3047248968 creator A5063216145 @default.
- W3047248968 date "2020-09-15" @default.
- W3047248968 modified "2023-10-16" @default.
- W3047248968 title "Visible‐Light Photoredox‐Catalyzed Remote Difunctionalizing Carboxylation of Unactivated Alkenes with CO<sub>2</sub>" @default.
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