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- W3047853614 abstract "The extraction of Mg2+ by di-(2-ethylhexyl) phosphoric acid (P204) was carried out to separate lithium and magnesium. To facilitate the direct electrodeposition of metallic magnesium from the magnesium-rich organic phase, different diluents and ionic liquids were investigated. It was found that tributylhexylphosphonium bis (trifluoromethyl sulfonyl) imide ionic liquid ([P4446][NTf2]) can serve as an excellent supporting electrolyte to solve the electroconductibility of the weak polarity organic phase. The electroconductivity was further increased by more than 1500 times by the use of methyl isobutyl ketone (MIBK) as a diluent. The single-stage extraction rate of Mg2+ at a concentration up to 76.87 g/L reached 68.4% using 40% P204 + 55% MIBK + 5% [P4446][NTf2] at R(O/A) = 6:1, and the electroconductivity of organic phase was 254.5 μS·cm−1 after extraction. The extraction mechanism and thermokinetics indicated that both [P4446][NTf2] and MIBK do not participate in the extraction process, and the extraction is an obvious endothermic process." @default.
- W3047853614 created "2020-08-13" @default.
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- W3047853614 date "2021-01-01" @default.
- W3047853614 modified "2023-10-12" @default.
- W3047853614 title "Separation of magnesium from high Mg/Li ratio brine by extraction with an organic system containing ionic liquid" @default.
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- W3047853614 doi "https://doi.org/10.1016/j.ces.2020.116019" @default.
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