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- W3047872021 abstract "Abstract The coupling of bridging diphenylphosphanides (PPh2–) with terminally bonded anionic ligands (L–) that takes place onto polynuclear Pt or Pd systems is reviewed. The two-electron reduction that accompanies the PPh2/L coupling generally implicates a M(IV) centre but there are examples where the redox process involves a M(II),M(II) system that is transformed into a M(I),M(I) containing product (M = Pd, Pt). The discussed coupling reactions end up with formation of new ligands which, depending on the nature of L–, display P–E bonds with E=C, N, O, P, S and I." @default.
- W3047872021 created "2020-08-13" @default.
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- W3047872021 date "2020-12-01" @default.
- W3047872021 modified "2023-10-18" @default.
- W3047872021 title "Platinum and palladium promoted couplings of bridging PPh2– with terminally bonded ligands" @default.
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- W3047872021 doi "https://doi.org/10.1016/j.ica.2020.119947" @default.
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