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• W3047883954 endingPage "3267" @default.
• W3047883954 startingPage "3259" @default.
• W3047883954 abstract "New diphenylmethane [4‐ t Bu‐2‐(C 3 H 2 N 2 Me‐1)C 6 H 3 ] 2 CH 2 ( 1 ) bearing pendant imidazolyl groups in ortho ‐positions of aromatic rings of diphenylmethane skeleton was synthesized using Stille cross‐coupling reaction between bis(4‐( tert ‐butyl)‐2‐iodophenyl)methane and Bu 3 Sn(C 3 H 2 N 2 Me) in the presence of Pd(PPh 3 ) 4 . Potassium diphenylmethanide [{[4‐ t Bu‐2‐(C 3 H 2 N 2 Me‐1)C 6 H 3 ] 2 CH}K(OEt 2 )] 2 ( 2 K ) was prepared by treatment of 1 with an equimolar amount of Lochmann‐Schlosser super base. Rare‐earth metal heteroalkyl complexes {[4‐ t Bu‐2‐(C 3 H 2 N 2 Me‐1)C 6 H 3 ] 2 CH}Ln(CH 2 SiMe 3 ) 2 (THF) n (Ln = Sc, n = 0 ( 2 Sc ); Y, n = 1 ( 2 Y )) with NC sp3 N pincer type diphenylmethanido ligand were synthesized by the selective sp 3 CH‐bond activation of the central CH 2 group in 1 by Ln(CH 2 SiMe 3 ) 3 (THF) 2 . According to the X‐ray data the diphenylmethanido ligands in 2 K and 2 Sc perform a tridentate pincer‐type κ 3 ‐N,C,N coordination. Complexes 2 Ln were evaluated as catalysts for isoprene polymerization and hydrosilylation of alkenes and alkynes." @default.
• W3047883954 created "2020-08-13" @default.
• W3047883954 creator A5005923402 @default.
• W3047883954 creator A5010517105 @default.
• W3047883954 creator A5037686757 @default.
• W3047883954 creator A5041459244 @default.
• W3047883954 creator A5049289774 @default.
• W3047883954 creator A5072554887 @default.
• W3047883954 creator A5075919510 @default.
• W3047883954 date "2020-08-30" @default.
• W3047883954 modified "2023-09-26" @default.
• W3047883954 title "Sc and Y Heteroalkyl Complexes with a NC _sp3 N Pincer‐Type Diphenylmethanido Ligand: Synthesis, Structure, and Reactivity" @default.
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