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• W3048002307 abstract "A new coordination polymer (CP), namely, poly[[diaquatris[μ 2 -1,4-bis(1 H -imidazol-1-yl)benzene]bis[μ 6 -4-(2,4-dicarboxylatophenoxy)phthalato]tetracobalt(II)] hexahydrate], {[Co 4 (C 16 H 6 O 9 ) 2 (C 12 H 10 N 4 ) 3 (H 2 O) 2 ]·6H 2 O} n , has been synthesized by solvothermal reaction. The CP was fully characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, and powder and single-crystal X-ray diffraction. It presents a three-dimensional (3D) structure based on tetranuclear Co II secondary building units (SBUs) with a tfz-d net and point symbol (4 3 ) 2 (4 6 ·6 18 ·8 4 ). The 4-(2,4-dicarboxyphenoxy)phthalic acid (H 4 dcppa) ligands are completely deprotonated and link {Co 4 (COO) 4 } 4− SBUs into two-dimensional (2D) layers. Furthermore, adjacent layers are connected by 1,4-bis(1 H -imidazol-1-yl)benzene (bib) ligands, giving rise to a 3D supramolecular architecture. Interestingly, there are numerous elliptical cavities in the CP where isolated unique discrete hexameric water clusters have been observed. The results of thermogravimetric and magnetic analyses are described in detail." @default.
• W3048002307 created "2020-08-13" @default.
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• W3048002307 date "2020-08-07" @default.
• W3048002307 modified "2023-10-08" @default.
• W3048002307 title "A novel three-dimensional tetranuclear CoII coordination polymer with water hexamers based on the V-shaped tetracarboxylate ligand 4-(2,4-dicarboxylatophenoxy)phthalate" @default.
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• W3048002307 doi "https://doi.org/10.1107/s2053229620010633" @default.
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