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- W3048133796 abstract "• Flavins photochemistry on the basis of new riboflavin derivative 3-benzylriboflavin. • Main photoproducts formed upon irradiation are determined. • Fragmentation pathways for new analogues, 3-benzylriboflavin and 2-thioriboflavin. • Combined analysis from photochemical and mass spectrometry point of view. • Similar structures are formed in photochemistry and in mass spectrometry. Flavins are compounds of important biological functions due to their photochemical and photophysical properties. We report photochemical properties in acetonitrile and mass spectrometric data of riboflavin analogue, 3-benzylriboflavin. In photochemical experiment there are formed two main (3-benzyllumichrome and 3-benzyllumiflavin) and five additional photoproducts, most of them of isoalloxazine structure. Photoproducts, identified by mass spectra, have been analyzed in comparison to the respective MS fragmentation patterns. Results for 3-benzylriboflavin was compared to those obtained for riboflavin and 2-thioriboflavin. EI-MS, ESI-MS and LC-HRMS methods have been used, the latter combined with the ESI techniques. The MS details combined with the photolysis data display some similarities, indicating the relative stability of some products formed upon UV-VIS irradiation and zfragmentation." @default.
- W3048133796 created "2020-08-13" @default.
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- W3048133796 date "2020-12-01" @default.
- W3048133796 modified "2023-10-17" @default.
- W3048133796 title "Riboflavin degradation products; combined photochemical and mass spectrometry approach" @default.
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- W3048133796 doi "https://doi.org/10.1016/j.jphotochem.2020.112837" @default.
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