FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3048152422> ?p ?o ?g. }

• W3048152422 endingPage "39144" @default.
• W3048152422 startingPage "39135" @default.
• W3048152422 abstract "The development of noncorrosive but highly efficient electrolytes has been a long-standing challenge in magnesium rechargeable battery (MRB) research fields. As fluorinated alkoxyborate-based electrolytes have overcome serious problems associated with conventional electrolytes, they are regarded as promising for practical MRB applications. An electrolyte containing representative magnesium fluorinated alkoxyborate Mg[B(HFIP)4]2 ([B(HFIP)4]: tetrakis(hexafluoroisopropoxy) borate) was prepared through general synthetic routes using Mg(BH4)2; however, it shows poor electrochemical magnesium deposition/dissolution behavior. Herein, we report an alternative synthetic route of highly reactive Mg[B(HFIP)4]2 and several critical issues associated with the use of Mg[B(HFIP)4]2/glyme electrolytes in MRBs. The cycling performance of the electrolytes as well as the synthetic reproducibility of the salt was significantly improved upon adopting a transmetalation reaction between certain magnesium and boron compounds for the salt preparation. Despite the outstanding electrochemical activity of Mg[B(HFIP)4]2/glyme, the electrolytes were unstable with the magnesium metal. The remarkably high dissociativity of Mg[B(HFIP)4]2 in glyme solutions and the resulting enhanced induction interaction of Mg2+ with coordinated glymes make the solutions reductively unstable. Surface passivation by [TFSA]-based electrolytes (TFSA: bis(trifluoromethanesulfonyl)amide) effectively suppressed the decomposition of Mg[B(HFIP)4]2/glyme electrolytes. This passivation simultaneously caused a large overpotential for electrochemical cycling. The short-circuiting of the cells upon repeated deposition/dissolution cycling is rather problematic. Here, the findings disclose the issues of fluorinated alkoxyborate-based electrolyte solutions that should be resolved for practical MRB materialization. We also emphasize the importance of systematic strategies in manipulating the electrolytes and interfaces as well as base magnesium metal based on each appropriate approach." @default.
• W3048152422 created "2020-08-13" @default.
• W3048152422 creator A5036698809 @default.
• W3048152422 date "2020-08-07" @default.
• W3048152422 modified "2023-10-03" @default.
• W3048152422 title "Critical Issues of Fluorinated Alkoxyborate-Based Electrolytes in Magnesium Battery Applications" @default.
• W3048152422 cites W1639753480 @default.
• W3048152422 cites W1996273492 @default.
• W3048152422 cites W1998524463 @default.
• W3048152422 cites W2127084638 @default.
• W3048152422 cites W2150697053 @default.
• W3048152422 cites W2152502531 @default.
• W3048152422 cites W2168007532 @default.
• W3048152422 cites W2239048326 @default.
• W3048152422 cites W2288498147 @default.
• W3048152422 cites W2309600546 @default.
• W3048152422 cites W2409636093 @default.
• W3048152422 cites W2553145141 @default.
• W3048152422 cites W2569249227 @default.
• W3048152422 cites W2571765347 @default.
• W3048152422 cites W2593064724 @default.
• W3048152422 cites W2604754163 @default.
• W3048152422 cites W2758176492 @default.
• W3048152422 cites W2769165467 @default.
• W3048152422 cites W2795577707 @default.
• W3048152422 cites W2883273814 @default.
• W3048152422 cites W2885622823 @default.
• W3048152422 cites W2905726631 @default.
• W3048152422 cites W2909993030 @default.
• W3048152422 cites W2912330672 @default.
• W3048152422 cites W2918926610 @default.
• W3048152422 cites W2921219874 @default.
• W3048152422 cites W2922232208 @default.
• W3048152422 cites W2937653710 @default.
• W3048152422 cites W2937757870 @default.
• W3048152422 cites W2937805902 @default.
• W3048152422 cites W2942968888 @default.
• W3048152422 cites W2954141204 @default.
• W3048152422 cites W2969434760 @default.
• W3048152422 cites W2969967587 @default.
• W3048152422 cites W2972590266 @default.
• W3048152422 cites W2979767071 @default.
• W3048152422 cites W2996721257 @default.
• W3048152422 cites W3015012665 @default.
• W3048152422 cites W3022311415 @default.
• W3048152422 cites W3024598097 @default.
• W3048152422 doi "https://doi.org/10.1021/acsami.0c09948" @default.
• W3048152422 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32805873" @default.
• W3048152422 hasPublicationYear "2020" @default.
• W3048152422 type Work @default.
• W3048152422 sameAs 3048152422 @default.
• W3048152422 citedByCount "57" @default.
• W3048152422 countsByYear W30481524222020 @default.
• W3048152422 countsByYear W30481524222021 @default.
• W3048152422 countsByYear W30481524222022 @default.
• W3048152422 countsByYear W30481524222023 @default.
• W3048152422 crossrefType "journal-article" @default.
• W3048152422 hasAuthorship W3048152422A5036698809 @default.
• W3048152422 hasConcept C121332964 @default.
• W3048152422 hasConcept C147789679 @default.
• W3048152422 hasConcept C163258240 @default.
• W3048152422 hasConcept C171250308 @default.
• W3048152422 hasConcept C17525397 @default.
• W3048152422 hasConcept C178790620 @default.
• W3048152422 hasConcept C179104552 @default.
• W3048152422 hasConcept C185592680 @default.
• W3048152422 hasConcept C186460083 @default.
• W3048152422 hasConcept C191897082 @default.
• W3048152422 hasConcept C192562407 @default.
• W3048152422 hasConcept C2776371256 @default.
• W3048152422 hasConcept C2779227376 @default.
• W3048152422 hasConcept C33574316 @default.
• W3048152422 hasConcept C52859227 @default.
• W3048152422 hasConcept C543218039 @default.
• W3048152422 hasConcept C555008776 @default.
• W3048152422 hasConcept C62520636 @default.
• W3048152422 hasConcept C68801617 @default.
• W3048152422 hasConcept C88380143 @default.
• W3048152422 hasConceptScore W3048152422C121332964 @default.
• W3048152422 hasConceptScore W3048152422C147789679 @default.
• W3048152422 hasConceptScore W3048152422C163258240 @default.
• W3048152422 hasConceptScore W3048152422C171250308 @default.
• W3048152422 hasConceptScore W3048152422C17525397 @default.
• W3048152422 hasConceptScore W3048152422C178790620 @default.
• W3048152422 hasConceptScore W3048152422C179104552 @default.
• W3048152422 hasConceptScore W3048152422C185592680 @default.
• W3048152422 hasConceptScore W3048152422C186460083 @default.
• W3048152422 hasConceptScore W3048152422C191897082 @default.
• W3048152422 hasConceptScore W3048152422C192562407 @default.
• W3048152422 hasConceptScore W3048152422C2776371256 @default.
• W3048152422 hasConceptScore W3048152422C2779227376 @default.
• W3048152422 hasConceptScore W3048152422C33574316 @default.
• W3048152422 hasConceptScore W3048152422C52859227 @default.
• W3048152422 hasConceptScore W3048152422C543218039 @default.
• W3048152422 hasConceptScore W3048152422C555008776 @default.
• W3048152422 hasConceptScore W3048152422C62520636 @default.
• W3048152422 hasConceptScore W3048152422C68801617 @default.
• W3048152422 hasConceptScore W3048152422C88380143 @default.

• next