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• W3048177766 abstract "A high-purity green-emitting Sr2(Mg,Mn)Al22O36 solid-solution phosphor and its partial doped compound (Sr2(Mg,Mn)Al22O36: Eu2+) were synthesized via solid-state reaction. This solid-solution phosphor shows a green band at 518 nm from Mn2+ instinct 4T1-6A1 transition with a narrow FWHM of 28 nm. This green emission is of high color purity (87.7%) and thermal stable (80% of original intensity at 473 K). However, the emission intensity requires further enhancement due to the limitation of Mn2+ 3d-3d forbidden transition. With a tiny amount of Eu2+ introduced into Sr2(Mg,Mn)Al22O36, the luminescence intensity enormously improved to 260% of that in blank sample due to high-efficient Eu2+-Mn2+ energy transfer, which is induced by a structural confinement effect with Eu2+-Mn2+ distance of 6.225 Å. Thus, the EQE of optimal phosphor Sr2Mg0·2Mn0·8Al22O36: 0.01Eu2+ is boosted to 42%. The above results hint that Sr2(Mg,Mn)Al22O36: Eu2+ has promising application potential as a green phosphor for backlighting LEDs in wide-color-gamut display, and this sensitized strategy could be applied for the development of high-performance phosphors." @default.
• W3048177766 created "2020-08-13" @default.
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• W3048177766 date "2020-12-01" @default.
• W3048177766 modified "2023-10-16" @default.
• W3048177766 title "Energy-transfer-induced enhancement of Mn2+-based narrow-band green emission in Sr2(Mg,Mn)Al22O36 phosphor by Eu2+ alloying" @default.
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• W3048177766 doi "https://doi.org/10.1016/j.ceramint.2020.07.328" @default.
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