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- W3048195324 endingPage "465402" @default.
- W3048195324 startingPage "465402" @default.
- W3048195324 abstract "Hierarchical nanoflowers (NFs) of zinc oxide (ZnO) have been synthesized in the hexagonal wurtzite structure by a facile hydrothermal method. Polyaniline (PANI) has been prepared by the chemical oxidative polymerization method and incorporated with ZnO NFs by the chemisorption method. The potential of the synthesized nanostructures has been demonstrated for efficient photocatalytic degradation of methylene blue (MB) and photoelectrochemical water splitting. The PANI/ZnO nanocomposite has exhibited the enhanced photocatalytic activity which is ∼9 fold higher in comparison to pristine ZnO NFs and enhanced photocurrent density which is ∼16 fold higher than the ZnO photoanode. Importantly, ∼4 fold increment in the incident photon-to-current conversion efficiency (IPCE) is exhibited by PANI/ZnO, than that of ZnO photoanode. The remarkably enhanced photocatalytic and photoelectrochemical performance of PANI/ZnO nanocomposite is attributed to the availability of more interfacial sites facilitated by the hierarchical ZnO NFs, improved overall photoresponse due to its photosensitization with PANI and the resulting type-II heterojunction between them, which helps in the efficient separation of photogenerated charge carriers at the interface. A plausible reaction mechanism for the substantially improved performance of nanostructured PANI/ZnO towards MB degradation and water splitting has also been elucidated." @default.
- W3048195324 created "2020-08-13" @default.
- W3048195324 creator A5024641130 @default.
- W3048195324 creator A5073415837 @default.
- W3048195324 creator A5091448100 @default.
- W3048195324 date "2020-08-28" @default.
- W3048195324 modified "2023-09-25" @default.
- W3048195324 title "Hierarchical PANI/ZnO nanocomposite: synthesis and synergistic effect of shape-selective ZnO nanoflowers and polyaniline sensitization for efficient photocatalytic dye degradation and photoelectrochemical water splitting" @default.
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