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- W3048199644 endingPage "11210" @default.
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- W3048199644 abstract "Three new dimeric bis-guanidinate zinc(II) alkyl, halide, and hydride complexes [LZnEt]2 (1), [LZnI]2 (2) and [LZnH]2 (3) were prepared. Compound 3 was successfully employed for the hydrosilylation and hydroboration of a vast number of ketones. The catalytic performance of 3 in the hydroboration of acetophenone exhibits a turnover frequency, reaching up to 5800 h–1, outperforming that of reported zinc hydride catalysts. Notably, both intra- and intermolecular chemoselective hydrosilylation and hydroboration reactions have been investigated." @default.
- W3048199644 created "2020-08-13" @default.
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- W3048199644 date "2020-08-06" @default.
- W3048199644 modified "2023-10-08" @default.
- W3048199644 title "Zinc Hydride-Catalyzed Hydrofuntionalization of Ketones" @default.
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- W3048199644 doi "https://doi.org/10.1021/acs.joc.0c01285" @default.
- W3048199644 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32786632" @default.
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