Matches in SemOpenAlex for { <https://semopenalex.org/work/W3048274766> ?p ?o ?g. }
- W3048274766 abstract "Abstract The importance, yet scarcity of the critical constants of thermally unstable fluids warrants the development of reliable methods for the estimation of these essential thermodynamic properties. A thorough investigation undertaken in this study on 1,589 compounds belonging to 83 chemical classes, indicated that the ratio of critical temperature to critical pressure of both low and high molecular weight compounds could be well expressed in terms of their volumetric properties. In addition, two new methodologies are presented for estimating V c , as well as an indirect approach for prediction of T c from surface tension data, altogether allowing the calculation of Z c . Moreover, comparative studies are made with five group contribution methods. It is also demonstrated that by employing the Peng‐Robinson EOS, and without prior knowledge of the critical properties, it is possible to calculate various thermophysical properties including P sat. , T b , , ∆H vap. , C p , and even the T c and P c themselves." @default.
- W3048274766 created "2020-08-13" @default.
- W3048274766 creator A5033698866 @default.
- W3048274766 creator A5046017320 @default.
- W3048274766 date "2020-08-31" @default.
- W3048274766 modified "2023-10-18" @default.
- W3048274766 title "Estimation of the critical properties of compounds using volume‐based thermodynamics" @default.
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- W3048274766 doi "https://doi.org/10.1002/aic.17004" @default.
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