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- W3048304327 abstract "Enhancing the dispersibility and conductivity is an effective solution to develop the application zeolitic imidazole frameworks (ZIF) in the electrochemical field. This work thus employs a novel reaction–diffusion framework (RDF) technique for the in situ growth of ZIF-8 crystals on graphene oxide ([email protected]) matrixes. In detail, the outer electrolyte of 2-methyl imidazole naturally diffuses into the inner agar gel matrix containing Zn2+ cations and GO nanosheets. The long reaction–diffusion makes the growth of ZIF-8 crystals controllable in a vertical gradient. After thermal treatment, the title product of ZIF-8 in situ grown on reduced graphene oxide ([email protected]) is obtained and thus exhibits good dispersibility, high conductivity, large surface area, and more catalytic sites. The glassy carbon electrode (GCE) was modified by casting the [email protected] suspension. The obtained [email protected]/GCE displays excellent catalytic activity toward naphthol (NAP) isomers. Under the optimal conditions, the amperometric currents of 1-NAP and 2-NAP demonstrate the good linear relationship in wide ranges of 0.05–12 μM and 0.02–15 μM, respectively. Their limits of detection are as low as 15 and 17 nM, respectively. The fabricated modified electrode exhibits excellent selectivity, stability, and reproducibility. The sensor is also utilized to detect NAP molecules in real water samples and indicates good accuracy and reliability." @default.
- W3048304327 created "2020-08-13" @default.
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- W3048304327 date "2021-01-01" @default.
- W3048304327 modified "2023-10-17" @default.
- W3048304327 title "Electrochemical sensing platform for naphthol isomers based on in situ growth of ZIF-8 on reduced graphene oxide by a reaction-diffusion technique" @default.
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- W3048304327 doi "https://doi.org/10.1016/j.jcis.2020.08.009" @default.
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