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• W3048366810 abstract "C–H activation with transition metal catalysis has become an important tool in organic synthesis for the functionalization of low reactive bonds and the preparation of complex molecules. The choice of the directing group (DG) proves to be crucial for the selectivity in this type of reaction, and several different functional groups have been used efficiently. This review describes recent advances in C–H functionalization of aromatic rings directed by a N-tosylcarboxamide group. Results regarding alkenylation, alkoxylation, halogenation, and arylation of C–H in the ortho position to the tosylcarboxamide are presented. Moreover, the advantage of this particular directing group is that it can undergo further transformation and act as CO or CON fragment reservoir to produce, in sequential fashion or one-pot sequence, various interesting (hetero)cycles such as phenanthridinones, dihydroisoquinolinones, fluorenones, or isoindolinones." @default.
• W3048366810 created "2020-08-18" @default.
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• W3048366810 date "2020-08-13" @default.
• W3048366810 modified "2023-10-11" @default.
• W3048366810 title "N-Tosylcarboxamide in C–H Functionalization: More than a Simple Directing Group" @default.
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• W3048366810 doi "https://doi.org/10.3390/pr8080981" @default.
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