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- W3048375835 abstract "Zn(II)-catalyzed divergent synthesis of functionalized polycyclic indolines through formal [3 + 2] and [4 + 2] cycloadditions of indoles with 1,2-diaza-1,3-dienes (DDs) is reported. The nature and type of substituents of substrates are found to act as a chemical switch to trigger two distinct reaction pathways and to obtain two different types of products upon the influence of the same catalyst. The mechanism of both [4 + 2] and [3 + 2] cycloadditions was investigated and fully rationalized by density functional theory (DFT) calculations." @default.
- W3048375835 created "2020-08-18" @default.
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- W3048375835 date "2020-08-12" @default.
- W3048375835 modified "2023-10-15" @default.
- W3048375835 title "Synthesis of Polycyclic Fused Indoline Scaffolds through a Substrate-Guided Reactivity Switch" @default.
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- W3048375835 doi "https://doi.org/10.1021/acs.joc.0c01489" @default.
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