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• W3048381777 abstract "Chalcogen-based urea compounds supported by a wide range of N-heterocyclic carbenes are synthesised and fully characterised. Coordination of selenoureas is further explored with Group 11 transition metals to form new copper, gold and silver complexes. Single crystal X-ray analyses unambiguously establish the solid-state coordination of these complexes and show that the geometry of a complex is highly influenced by a combination of electronic properties - mainly π-accepting ability - and steric hindrance of the ligands, as well as the nature of the metal, affording a variety of coordination behaviours. In this report, we investigate these phenomena using several experimental methods." @default.
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• W3048381777 date "2020-01-01" @default.
• W3048381777 modified "2023-10-16" @default.
• W3048381777 title "Straightforward access to chalcogenoureas derived from N-heterocyclic carbenes and their coordination chemistry" @default.
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• W3048381777 doi "https://doi.org/10.1039/d0dt02558e" @default.
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