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- W3048382604 endingPage "127920" @default.
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- W3048382604 abstract "Arsenic (As) and selenium (Se) pollution caused by coal combustion is receiving increasing concerns. The environmental impacts of As/Se are determined not only by stack emission but also by leaching process from combustion byproducts. For a better control of As/Se emission from As/Se-enriched coal combustion, this study investigated the migration and emission behavior of As/Se in a circulating fluidized bed (CFB) power plant equipped with fabric filter (FF) and wet flue gas desulfurization (WFGD) system. The results demonstrated that arsenic was both enriched in bottom ash (41.4–47.6%) and fly ash (52.4–58.6%), while selenium was mainly captured by fly ash (73.9–83.4%). Limestone injection into furnace promoted As/Se retention in ash residues. Arsenic was mainly converted into arsenate in high-temperature regions and partly trapped in bottom ash as arsenite. In contrast, selenium capture mainly occurred in low-temperature flue gas by the formation of selenite, because of the poor thermal stability of most selenite. Triplet-tank method can totally remove arsenic in WFGD wastewater. And 18.4–58.7% of selenium was removed, resulting from the precipitation of Se4+ anions with highly soluble Se6+ anions remaining in wastewater. The concentrations of As and Se in the stack emission were 0.25–1.02 and 0.96–2.24 μg/m3, receptively. The CFB boiler equipped with FF + WFGD was shown to provide good control of the As/Se emission into the atmosphere. Leaching tests suggested that more attention should be paid to As leachability from fly ash/gypsum, and Se leachability from gypsum/sludge." @default.
- W3048382604 created "2020-08-18" @default.
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- W3048382604 date "2021-01-01" @default.
- W3048382604 modified "2023-09-29" @default.
- W3048382604 title "Migration and emission behavior of arsenic and selenium in a circulating fluidized bed power plant burning arsenic/selenium-enriched coal" @default.
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- W3048382604 doi "https://doi.org/10.1016/j.chemosphere.2020.127920" @default.
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