Matches in SemOpenAlex for { <https://semopenalex.org/work/W3048411204> ?p ?o ?g. }
- W3048411204 endingPage "1820" @default.
- W3048411204 startingPage "1820" @default.
- W3048411204 abstract "Surface modification of nanoparticles with functional molecules has become a routine method to compensate for diffusion-controlled crosslinking of thermoset polymer composites at late stages of crosslinking, while bulk modification has not carefully been discussed. In this work, a highly-crosslinked model polymer nanocomposite based on epoxy and surface-bulk functionalized magnetic nanoparticles (MNPs) was developed. MNPs were synthesized electrochemically, and then polyethylene glycol (PEG) surface-functionalized (PEG-MNPs) and PEG-functionalized cobalt-doped (Co-PEG-MNPs) particles were developed and used in nanocomposite preparation. Various analyses including field-emission scanning electron microscopy, Fourier-transform infrared spectrophotometry (FTIR), thermogravimetric analysis (TGA), X-ray diffraction (XRD) and vibrating sample magnetometry (VSM) were employed in characterization of surface and bulk of PEG-MNPs and Co-PEG-MNPs. Epoxy nanocomposites including the aforementioned MNPs were prepared and analyzed by nonisothermal differential scanning calorimetry (DSC) to study their curing potential in epoxy/amine system. Analyses based on Cure Index revealed that incorporation of 0.1 wt.% of Co-PEG-MNPs into epoxy led to Excellent cure at all heating rates, which uncovered the assistance of bulk modification of nanoparticles to the crosslinking of model epoxy nanocomposites. Isoconversional methods revealed higher activation energy for the completely crosslinked epoxy/Co-PEG-MNPs nanocomposite compared to the neat epoxy. The kinetic model based on isoconversional methods was verified by the experimental rate of cure reaction." @default.
- W3048411204 created "2020-08-18" @default.
- W3048411204 creator A5002056699 @default.
- W3048411204 creator A5051012048 @default.
- W3048411204 creator A5059884896 @default.
- W3048411204 creator A5076958678 @default.
- W3048411204 creator A5089503809 @default.
- W3048411204 creator A5091101096 @default.
- W3048411204 date "2020-08-13" @default.
- W3048411204 modified "2023-09-26" @default.
- W3048411204 title "Bulk-Surface Modification of Nanoparticles for Developing Highly-Crosslinked Polymer Nanocomposites" @default.
- W3048411204 cites W1964927587 @default.
- W3048411204 cites W1969945203 @default.
- W3048411204 cites W1973887862 @default.
- W3048411204 cites W1991773387 @default.
- W3048411204 cites W2001308987 @default.
- W3048411204 cites W2012125195 @default.
- W3048411204 cites W2012257367 @default.
- W3048411204 cites W2022643741 @default.
- W3048411204 cites W2032296440 @default.
- W3048411204 cites W2153076352 @default.
- W3048411204 cites W2518600031 @default.
- W3048411204 cites W2592433514 @default.
- W3048411204 cites W2612440300 @default.
- W3048411204 cites W2616230076 @default.
- W3048411204 cites W2618572920 @default.
- W3048411204 cites W2747920770 @default.
- W3048411204 cites W2749179813 @default.
- W3048411204 cites W2751464040 @default.
- W3048411204 cites W2758628458 @default.
- W3048411204 cites W2766467551 @default.
- W3048411204 cites W2766737656 @default.
- W3048411204 cites W2767179885 @default.
- W3048411204 cites W2770640068 @default.
- W3048411204 cites W2776517291 @default.
- W3048411204 cites W2778871440 @default.
- W3048411204 cites W2790717154 @default.
- W3048411204 cites W2804228280 @default.
- W3048411204 cites W2807727302 @default.
- W3048411204 cites W2809173415 @default.
- W3048411204 cites W2884647224 @default.
- W3048411204 cites W2891780408 @default.
- W3048411204 cites W2910263859 @default.
- W3048411204 cites W2911444951 @default.
- W3048411204 cites W2920906294 @default.
- W3048411204 cites W2943637726 @default.
- W3048411204 cites W2956128118 @default.
- W3048411204 cites W2963292474 @default.
- W3048411204 cites W2969463585 @default.
- W3048411204 cites W2969519247 @default.
- W3048411204 cites W2970242148 @default.
- W3048411204 cites W2972414211 @default.
- W3048411204 cites W2974824888 @default.
- W3048411204 cites W2978383223 @default.
- W3048411204 cites W3011920944 @default.
- W3048411204 cites W3016898951 @default.
- W3048411204 cites W3024270610 @default.
- W3048411204 cites W3033514603 @default.
- W3048411204 cites W4230984356 @default.
- W3048411204 cites W4231897154 @default.
- W3048411204 cites W4232854237 @default.
- W3048411204 cites W4234823207 @default.
- W3048411204 cites W4234866118 @default.
- W3048411204 cites W4239293933 @default.
- W3048411204 cites W4246492506 @default.
- W3048411204 cites W887647896 @default.
- W3048411204 doi "https://doi.org/10.3390/polym12081820" @default.
- W3048411204 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7465673" @default.
- W3048411204 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32823709" @default.
- W3048411204 hasPublicationYear "2020" @default.
- W3048411204 type Work @default.
- W3048411204 sameAs 3048411204 @default.
- W3048411204 citedByCount "6" @default.
- W3048411204 countsByYear W30484112042020 @default.
- W3048411204 countsByYear W30484112042021 @default.
- W3048411204 countsByYear W30484112042022 @default.
- W3048411204 crossrefType "journal-article" @default.
- W3048411204 hasAuthorship W3048411204A5002056699 @default.
- W3048411204 hasAuthorship W3048411204A5051012048 @default.
- W3048411204 hasAuthorship W3048411204A5059884896 @default.
- W3048411204 hasAuthorship W3048411204A5076958678 @default.
- W3048411204 hasAuthorship W3048411204A5089503809 @default.
- W3048411204 hasAuthorship W3048411204A5091101096 @default.
- W3048411204 hasBestOaLocation W30484112041 @default.
- W3048411204 hasConcept C10138342 @default.
- W3048411204 hasConcept C115537861 @default.
- W3048411204 hasConcept C121332964 @default.
- W3048411204 hasConcept C127413603 @default.
- W3048411204 hasConcept C155672457 @default.
- W3048411204 hasConcept C159985019 @default.
- W3048411204 hasConcept C160892712 @default.
- W3048411204 hasConcept C162324750 @default.
- W3048411204 hasConcept C166595027 @default.
- W3048411204 hasConcept C171250308 @default.
- W3048411204 hasConcept C188027245 @default.
- W3048411204 hasConcept C192562407 @default.
- W3048411204 hasConcept C2776964284 @default.
- W3048411204 hasConcept C39519442 @default.