Matches in SemOpenAlex for { <https://semopenalex.org/work/W3048449719> ?p ?o ?g. }
- W3048449719 endingPage "6554" @default.
- W3048449719 startingPage "6545" @default.
- W3048449719 abstract "Three heterometallic Fe6Ln4 clusters were self-assembled by using N-methyldiethanolamine (H2mdea) and 3,5-dinitrobenzoic acid (Hdnbz) as principal building blocks and azide as an ancillary ligand. The obtained products 1–3 were isolated as air-stable microcrystalline solids and fully characterized. Single-crystal X-ray diffraction studies reveal similar type of molecular units [Fe6Ln4(μ4-O)2(μ3-OH)2(mdea)6(dnbz)8(N3)4]·2MeCN·xH2O·CH2Cl2 {Ln = Y (1), Gd (2), Dy (3); x = 4, 6, 10, respectively}. Topological analysis of 1–3 was performed following a method for high nuclearity coordination clusters. The [Fe6Ln4(μ-O)10(μ3-O)4(μ4-O)2] cores were identified in all structures and further simplified to graph topological skeletons, which were classified as pentanodal 2,3,3,5,6-connected motifs with the unique topology. The magnetic behavior of 1–3 was investigated in detail. The magnetic studies and magnetocaloric measurements reveal that the tetranuclear gadolinium centers of 2 exhibit a high cryogenic magnetocaloric effect (MCE) that reaches 13.66 J·kg–1·K–1 (25.18 mJ·cm–3·K–1) for ΔH = 90 kOe at 4.5 K. Among all the compounds, only 3 shows the ac-signals (ac, alternating current) and slow-relaxation behavior, which is a peculiar characteristic of a single-molecule magnet (SMM), giving a value of Ueff = 19.5(4) K. The present work thus contributes to the design of topologically unique discrete crystalline materials with notable functional properties." @default.
- W3048449719 created "2020-08-18" @default.
- W3048449719 creator A5008626158 @default.
- W3048449719 creator A5014181783 @default.
- W3048449719 creator A5045163988 @default.
- W3048449719 creator A5051926310 @default.
- W3048449719 creator A5079387142 @default.
- W3048449719 date "2020-08-13" @default.
- W3048449719 modified "2023-10-11" @default.
- W3048449719 title "Heterometallic (3d-4f) Coordination Clusters with Unique Topology: Self-Assembly Synthesis, Structural Features, and Magnetic Properties" @default.
- W3048449719 cites W1790298317 @default.
- W3048449719 cites W1963549236 @default.
- W3048449719 cites W1963754464 @default.
- W3048449719 cites W1971110974 @default.
- W3048449719 cites W1973081432 @default.
- W3048449719 cites W1974124936 @default.
- W3048449719 cites W1978708968 @default.
- W3048449719 cites W1978964278 @default.
- W3048449719 cites W1980049034 @default.
- W3048449719 cites W1980082634 @default.
- W3048449719 cites W1996401272 @default.
- W3048449719 cites W1999931095 @default.
- W3048449719 cites W2003016584 @default.
- W3048449719 cites W2004152551 @default.
- W3048449719 cites W2009426629 @default.
- W3048449719 cites W2010630242 @default.
- W3048449719 cites W2012903472 @default.
- W3048449719 cites W2028211551 @default.
- W3048449719 cites W2030189760 @default.
- W3048449719 cites W2030385807 @default.
- W3048449719 cites W2031948565 @default.
- W3048449719 cites W2032966107 @default.
- W3048449719 cites W2034707977 @default.
- W3048449719 cites W2039598271 @default.
- W3048449719 cites W2039858314 @default.
- W3048449719 cites W2043480712 @default.
- W3048449719 cites W2045894490 @default.
- W3048449719 cites W2055957828 @default.
- W3048449719 cites W2061353590 @default.
- W3048449719 cites W2068023207 @default.
- W3048449719 cites W2077520792 @default.
- W3048449719 cites W2079112305 @default.
- W3048449719 cites W2083494937 @default.
- W3048449719 cites W2096244632 @default.
- W3048449719 cites W2102472028 @default.
- W3048449719 cites W2110081012 @default.
- W3048449719 cites W2111415680 @default.
- W3048449719 cites W2117867509 @default.
- W3048449719 cites W2131350133 @default.
- W3048449719 cites W2145640516 @default.
- W3048449719 cites W2145776938 @default.
- W3048449719 cites W2145956699 @default.
- W3048449719 cites W2146099614 @default.
- W3048449719 cites W2153714253 @default.
- W3048449719 cites W2159610758 @default.
- W3048449719 cites W2166885579 @default.
- W3048449719 cites W2177071934 @default.
- W3048449719 cites W2252783088 @default.
- W3048449719 cites W2259045237 @default.
- W3048449719 cites W2329722358 @default.
- W3048449719 cites W2333416879 @default.
- W3048449719 cites W2382580658 @default.
- W3048449719 cites W2491438400 @default.
- W3048449719 cites W2511490285 @default.
- W3048449719 cites W2582897128 @default.
- W3048449719 cites W2586222003 @default.
- W3048449719 cites W2606689638 @default.
- W3048449719 cites W2610291086 @default.
- W3048449719 cites W2766327289 @default.
- W3048449719 cites W2767218075 @default.
- W3048449719 cites W2785198363 @default.
- W3048449719 cites W2786333913 @default.
- W3048449719 cites W2789831982 @default.
- W3048449719 cites W2790268956 @default.
- W3048449719 cites W2803762822 @default.
- W3048449719 cites W2808081610 @default.
- W3048449719 cites W2808184064 @default.
- W3048449719 cites W2885974887 @default.
- W3048449719 cites W2917680350 @default.
- W3048449719 cites W2952752172 @default.
- W3048449719 cites W2964218910 @default.
- W3048449719 cites W2968863967 @default.
- W3048449719 cites W3011810113 @default.
- W3048449719 cites W3098869859 @default.
- W3048449719 cites W3102983409 @default.
- W3048449719 doi "https://doi.org/10.1021/acs.cgd.0c00737" @default.
- W3048449719 hasPublicationYear "2020" @default.
- W3048449719 type Work @default.
- W3048449719 sameAs 3048449719 @default.
- W3048449719 citedByCount "20" @default.
- W3048449719 countsByYear W30484497192021 @default.
- W3048449719 countsByYear W30484497192022 @default.
- W3048449719 countsByYear W30484497192023 @default.
- W3048449719 crossrefType "journal-article" @default.
- W3048449719 hasAuthorship W3048449719A5008626158 @default.
- W3048449719 hasAuthorship W3048449719A5014181783 @default.
- W3048449719 hasAuthorship W3048449719A5045163988 @default.
- W3048449719 hasAuthorship W3048449719A5051926310 @default.