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• W3048467098 abstract "A NiO–Ni foam composite carrier was prepared by the hydrothermal method. Ruthenium metal was supported on the NiO–Ni foam by electroplating, obtaining a highly active bush-like Ru/NiO–Ni foam catalyst. To investigate the effect of NiO on the structure and performance of the catalyst, a Ru/Ni foam catalyst was prepared as a reference. The structures of the carrier and both catalysts were characterized by X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy, and the performances of both catalysts were evaluated in alcoholytic hydrogen production from sodium borohydride. On the carrier with the NiO-treated surface, the active component Ru developed a three-dimensional bush-like structure that enhanced the catalytic activity. Indeed, the hydrogen production from alcoholysis of sodium borohydride was three times higher on the Ru/NiO–Ni foam catalyst than on the Ru/Ni foam catalyst, and the highest rate exceeded 6 L/g/min. The repeated-use stability of the Ru/NiO–Ni catalyst (10 times) also exceeded that of Ru/Ni foam (8 times). However, as both catalysts used the same active component (i.e., Ru), their activation energies were almost identical." @default.
• W3048467098 created "2020-08-18" @default.
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• W3048467098 date "2020-08-10" @default.
• W3048467098 modified "2023-10-13" @default.
• W3048467098 title "Preparation of Bush-Like Ru/NiO-Ni Foam Catalyst and Its Performance in Hydrogen Production from Sodium Borohydride Alcoholysis" @default.
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• W3048467098 doi "https://doi.org/10.1021/acs.energyfuels.0c02190" @default.
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