FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3048474557> ?p ?o ?g. }

• W3048474557 abstract "We report the discovery of a trigonal polymorph of the prospective Li-ion battery material ${mathrm{Li}}_{2}mathrm{Mn}{mathrm{O}}_{3}$ and its synthesis in bulk, single-crystal form. Crystal growth of trigonal ${mathrm{Li}}_{2}mathrm{Mn}{mathrm{O}}_{3}$ is strongly dependent upon the quality of a polycrystalline $mathrm{Li}mathrm{Mn}{mathrm{O}}_{2}$ precursor consumed in the synthesis process. The crystal structure of the trigonal phase is composed of ordered honeycomb layers of $mathrm{Li}{mathrm{O}}_{6}$ and $mathrm{Mn}{mathrm{O}}_{6}$ octahedra segregated by layers of $mathrm{Li}{mathrm{O}}_{6}$ octahedra and represents an ordered stacking variant of the known monoclinic polymorph. Diffuse reflectance spectroscopy reveals a direct optical gap of $2.47ifmmodepmelsetextpmfi{}0.11$ eV and a series of charge excitations that are well explained by the expected ${mathrm{Mn}}^{4+}phantom{rule{4pt}{0ex}}3{d}^{3}$ valence. Density functional theory calculations are in excellent agreement with the spectroscopic measurements and find a near degeneracy in the formation energies of the two polymorphs. Our results suggest that the trigonal structure resolves the compositional and structural disorder often manifested in the monoclinic phase." @default.
• W3048474557 created "2020-08-18" @default.
• W3048474557 creator A5006242369 @default.
• W3048474557 creator A5014608105 @default.
• W3048474557 creator A5037535334 @default.
• W3048474557 creator A5048752016 @default.
• W3048474557 creator A5077905750 @default.
• W3048474557 creator A5080034867 @default.
• W3048474557 creator A5080102117 @default.
• W3048474557 creator A5087181882 @default.
• W3048474557 date "2020-08-10" @default.
• W3048474557 modified "2023-10-03" @default.
• W3048474557 title "Trigonal polymorph of <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:msub><mml:mi mathvariant=normal>Li</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:mi>Mn</mml:mi><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:math>" @default.
• W3048474557 cites W1522904452 @default.
• W3048474557 cites W1536745570 @default.
• W3048474557 cites W1979544533 @default.
• W3048474557 cites W1981368803 @default.
• W3048474557 cites W1988648323 @default.
• W3048474557 cites W1989436913 @default.
• W3048474557 cites W1992985800 @default.
• W3048474557 cites W1999292430 @default.
• W3048474557 cites W2007395042 @default.
• W3048474557 cites W2015197254 @default.
• W3048474557 cites W2017151442 @default.
• W3048474557 cites W2028056984 @default.
• W3048474557 cites W2030525182 @default.
• W3048474557 cites W2052523499 @default.
• W3048474557 cites W2054609282 @default.
• W3048474557 cites W2062666970 @default.
• W3048474557 cites W2069818993 @default.
• W3048474557 cites W2076621565 @default.
• W3048474557 cites W2081117603 @default.
• W3048474557 cites W2083222334 @default.
• W3048474557 cites W2091729323 @default.
• W3048474557 cites W2093052949 @default.
• W3048474557 cites W2094676522 @default.
• W3048474557 cites W2109372467 @default.
• W3048474557 cites W2131923220 @default.
• W3048474557 cites W2165528549 @default.
• W3048474557 cites W2240693357 @default.
• W3048474557 cites W2297470781 @default.
• W3048474557 cites W2320465721 @default.
• W3048474557 cites W2325410249 @default.
• W3048474557 cites W2327828477 @default.
• W3048474557 cites W2330095168 @default.
• W3048474557 cites W2330774784 @default.
• W3048474557 cites W2508319161 @default.
• W3048474557 cites W2560929385 @default.
• W3048474557 cites W2591932046 @default.
• W3048474557 cites W2612930702 @default.
• W3048474557 cites W2766367920 @default.
• W3048474557 cites W2784831063 @default.
• W3048474557 cites W2811085093 @default.
• W3048474557 cites W2886177874 @default.
• W3048474557 cites W2909380760 @default.
• W3048474557 cites W2951813533 @default.
• W3048474557 cites W2969375729 @default.
• W3048474557 cites W2974295261 @default.
• W3048474557 cites W2983468091 @default.
• W3048474557 cites W2995855191 @default.
• W3048474557 cites W2999368823 @default.
• W3048474557 cites W3016306463 @default.
• W3048474557 cites W3040352358 @default.
• W3048474557 cites W3099236362 @default.
• W3048474557 cites W3103566548 @default.
• W3048474557 cites W3106413352 @default.
• W3048474557 doi "https://doi.org/10.1103/physrevmaterials.4.085401" @default.
• W3048474557 hasPublicationYear "2020" @default.
• W3048474557 type Work @default.
• W3048474557 sameAs 3048474557 @default.
• W3048474557 citedByCount "2" @default.
• W3048474557 countsByYear W30484745572021 @default.
• W3048474557 countsByYear W30484745572023 @default.
• W3048474557 crossrefType "journal-article" @default.
• W3048474557 hasAuthorship W3048474557A5006242369 @default.
• W3048474557 hasAuthorship W3048474557A5014608105 @default.
• W3048474557 hasAuthorship W3048474557A5037535334 @default.
• W3048474557 hasAuthorship W3048474557A5048752016 @default.
• W3048474557 hasAuthorship W3048474557A5077905750 @default.
• W3048474557 hasAuthorship W3048474557A5080034867 @default.
• W3048474557 hasAuthorship W3048474557A5080102117 @default.
• W3048474557 hasAuthorship W3048474557A5087181882 @default.
• W3048474557 hasBestOaLocation W30484745572 @default.
• W3048474557 hasConcept C115624301 @default.
• W3048474557 hasConcept C121332964 @default.
• W3048474557 hasConcept C168900304 @default.
• W3048474557 hasConcept C185592680 @default.
• W3048474557 hasConcept C192562407 @default.
• W3048474557 hasConcept C194185919 @default.
• W3048474557 hasConcept C198819137 @default.
• W3048474557 hasConcept C61276311 @default.
• W3048474557 hasConcept C62520636 @default.
• W3048474557 hasConcept C8010536 @default.
• W3048474557 hasConceptScore W3048474557C115624301 @default.
• W3048474557 hasConceptScore W3048474557C121332964 @default.
• W3048474557 hasConceptScore W3048474557C168900304 @default.
• W3048474557 hasConceptScore W3048474557C185592680 @default.
• W3048474557 hasConceptScore W3048474557C192562407 @default.
• W3048474557 hasConceptScore W3048474557C194185919 @default.
• W3048474557 hasConceptScore W3048474557C198819137 @default.

• next