FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3048477190> ?p ?o ?g. }

• W3048477190 endingPage "149" @default.
• W3048477190 startingPage "136" @default.
• W3048477190 abstract "This work presents a comparative study on the pyrolysis of C8–C10 linear alkylbenzenes including ethylbenzene, n-propylbenzene and n-butylbenzene. Experiments were performed with highly diluted mixtures in argon containing respectively the three fuels under nearly identical conditions in a single-pulse shock tube, at a nominal pressure of 20 bar and over a temperature range of 950–1700 K. Post-shock gas mixtures were sampled and analyzed with the gas chromatographic technique so that species concentration evolutions as function of temperature were obtained for the pyrolysis of each fuel. A kinetic model was developed to interpret the similarities and differences regarding the fuel decomposition and species formation behaviors observed in the experiments. The fuel conversion of n-propylbenzene and n-butylbenzene proceeds along a similar curve, which is much faster than that of ethylbenzene. All three fuels are consumed mainly through the bond fission producing benzyl radical. The simultaneously formed C1–C3 alkyl radicals in separate cases significantly impact the fuel reactivity and the formation of small C1–C4 and monocyclic aromatic hydrocarbons. Specifically, in n-propylbenzene pyrolysis, the decomposition of ethyl radicals produces a considerable amount of hydrogen atoms, which enhances the reactivity of the reaction system and meanwhile results in relatively high production of benzene during the fuel consumption. The formation of other monocyclic aromatic hydrocarbon intermediates, such as toluene and styrene, is also influenced by fuel-related pathways. Concerning PAH formation, the kinetic schemes in the pyrolysis of linear C8–C10 alkylbenzenes are very similar, which are dominated by the reactions of benzyl and other resonantly-stabilized radicals produced from benzyl decomposition. The major PAH formation reactions are barely influenced by the fuel chemistry. The only notable fuel-specific pathway is the indene formation from 1-phenyl-2-propenyl in n-propylbenzene and n-butylbenzene pyrolysis at relatively low temperatures. Styrene is an abundant product and its reaction with phenyl is found to be an important channel of phenanthrene formation." @default.
• W3048477190 created "2020-08-18" @default.
• W3048477190 creator A5021122694 @default.
• W3048477190 creator A5028727210 @default.
• W3048477190 creator A5044964838 @default.
• W3048477190 creator A5052975299 @default.
• W3048477190 creator A5091435425 @default.
• W3048477190 date "2020-11-01" @default.
• W3048477190 modified "2023-10-18" @default.
• W3048477190 title "A comparative kinetic study of C8–C10 linear alkylbenzenes pyrolysis in a single-pulse shock tube" @default.
• W3048477190 cites W1970185735 @default.
• W3048477190 cites W1978954052 @default.
• W3048477190 cites W1981254574 @default.
• W3048477190 cites W1984920877 @default.
• W3048477190 cites W1986900171 @default.
• W3048477190 cites W1988043544 @default.
• W3048477190 cites W1991824412 @default.
• W3048477190 cites W1994973833 @default.
• W3048477190 cites W2000328474 @default.
• W3048477190 cites W2012952975 @default.
• W3048477190 cites W2013840038 @default.
• W3048477190 cites W2025824624 @default.
• W3048477190 cites W2031737292 @default.
• W3048477190 cites W2032478910 @default.
• W3048477190 cites W2041186015 @default.
• W3048477190 cites W2044951668 @default.
• W3048477190 cites W2048344933 @default.
• W3048477190 cites W2050270215 @default.
• W3048477190 cites W2052872009 @default.
• W3048477190 cites W2054713895 @default.
• W3048477190 cites W2056049232 @default.
• W3048477190 cites W2058032264 @default.
• W3048477190 cites W2058597996 @default.
• W3048477190 cites W2058856966 @default.
• W3048477190 cites W2064873435 @default.
• W3048477190 cites W2066396805 @default.
• W3048477190 cites W2070565777 @default.
• W3048477190 cites W2084418878 @default.
• W3048477190 cites W2130168279 @default.
• W3048477190 cites W2162115791 @default.
• W3048477190 cites W225987337 @default.
• W3048477190 cites W2279124537 @default.
• W3048477190 cites W2282858089 @default.
• W3048477190 cites W2423339577 @default.
• W3048477190 cites W2460923937 @default.
• W3048477190 cites W2770081556 @default.
• W3048477190 cites W2773411653 @default.
• W3048477190 cites W2799549605 @default.
• W3048477190 cites W2884504909 @default.
• W3048477190 cites W2885353716 @default.
• W3048477190 cites W2900341065 @default.
• W3048477190 cites W2943213596 @default.
• W3048477190 cites W2950299540 @default.
• W3048477190 cites W2966528266 @default.
• W3048477190 cites W3043649110 @default.
• W3048477190 cites W4247129227 @default.
• W3048477190 doi "https://doi.org/10.1016/j.combustflame.2020.07.031" @default.
• W3048477190 hasPublicationYear "2020" @default.
• W3048477190 type Work @default.
• W3048477190 sameAs 3048477190 @default.
• W3048477190 citedByCount "14" @default.
• W3048477190 countsByYear W30484771902021 @default.
• W3048477190 countsByYear W30484771902022 @default.
• W3048477190 countsByYear W30484771902023 @default.
• W3048477190 crossrefType "journal-article" @default.
• W3048477190 hasAuthorship W3048477190A5021122694 @default.
• W3048477190 hasAuthorship W3048477190A5028727210 @default.
• W3048477190 hasAuthorship W3048477190A5044964838 @default.
• W3048477190 hasAuthorship W3048477190A5052975299 @default.
• W3048477190 hasAuthorship W3048477190A5091435425 @default.
• W3048477190 hasBestOaLocation W30484771901 @default.
• W3048477190 hasConcept C121332964 @default.
• W3048477190 hasConcept C122881758 @default.
• W3048477190 hasConcept C139066938 @default.
• W3048477190 hasConcept C160434732 @default.
• W3048477190 hasConcept C178790620 @default.
• W3048477190 hasConcept C185592680 @default.
• W3048477190 hasConcept C2777207669 @default.
• W3048477190 hasConcept C2777691172 @default.
• W3048477190 hasConcept C2778142098 @default.
• W3048477190 hasConcept C2779348937 @default.
• W3048477190 hasConcept C2779533485 @default.
• W3048477190 hasConcept C36759035 @default.
• W3048477190 hasConcept C70477161 @default.
• W3048477190 hasConcept C75473681 @default.
• W3048477190 hasConcept C97355855 @default.
• W3048477190 hasConceptScore W3048477190C121332964 @default.
• W3048477190 hasConceptScore W3048477190C122881758 @default.
• W3048477190 hasConceptScore W3048477190C139066938 @default.
• W3048477190 hasConceptScore W3048477190C160434732 @default.
• W3048477190 hasConceptScore W3048477190C178790620 @default.
• W3048477190 hasConceptScore W3048477190C185592680 @default.
• W3048477190 hasConceptScore W3048477190C2777207669 @default.
• W3048477190 hasConceptScore W3048477190C2777691172 @default.
• W3048477190 hasConceptScore W3048477190C2778142098 @default.
• W3048477190 hasConceptScore W3048477190C2779348937 @default.
• W3048477190 hasConceptScore W3048477190C2779533485 @default.
• W3048477190 hasConceptScore W3048477190C36759035 @default.

• next