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- W3048497473 abstract "Novel dendritic micro-mesoporous TS-1/dendritic mesoporous silica nanoparticle (DMSN) composites (TD) were assembled by TS-1 nanocrystals with ultrasmall particle size and strong acidity. TS-1 seeds and DMSNs were composited via the Ti-O-Si chemical bond, which stimulate the generation of Brønsted (B) and Lewis (L) acids. The spillover d-electrons produced by the Ti element of TS-1 seeds produced a spillover of d-electrons, which could interact with the surface of MoS2 phases, thereby reducing Mo-S interactions and create sulfur vacancies that are favorable for dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT) hydrodesulfurization (HDS) reactions. The increased amount of B&L acid of NiMo/TD-2.0 with cetyltrimethylammonium bromide/sodium salicylate molar ratio of 2.0 played an important role in facilitating the hydrogenation (HYD) route of DBT HDS and the isomerization (ISO) route of 4,6-DMDBT HDS, which is more favorable for the reduction of steric hindrance of DBT and 4,6-DMDBT reactants in the HDS reaction process. The NiMo/TD-2.0 catalyst exhibited the highest turnover frequency (TOF) value and HDS reaction rate constant (kHDS) of DBT and 4,6-DMDBT due to its ultrasmall particle size, uniform spherical dendritic morphology, strong B&L acidity, and good stacking degree." @default.
- W3048497473 created "2020-08-18" @default.
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- W3048497473 date "2020-08-11" @default.
- W3048497473 modified "2023-10-17" @default.
- W3048497473 title "Structural Screening and Design of Dendritic Micro–Mesoporous Composites for Efficient Hydrodesulfurization of Dibenzothiophene and 4,6-Dimethyldibenzothiophene" @default.
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- W3048497473 doi "https://doi.org/10.1021/acsami.0c12631" @default.
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