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- W3048499528 endingPage "9742" @default.
- W3048499528 startingPage "9675" @default.
- W3048499528 abstract "Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear metallocycles with intratrimer metal-metal interactions are fascinating and important metal-organic or organometallic π-acids/bases. Each CTC of characteristic planar or near-planar trimetal nine-membered rings consists of Au(I)/Ag(I)/Cu(I) cations that linearly coordinate with N and/or C atoms in ditopic anionic bridging ligands. Since the first discovery of Au(I) CTC in the 1970s, research of CTCs has involved several fundamental areas, including noncovalent and metallophilic interaction, excimer/exciplex, acid-base chemistry, metalloaromaticity, supramolecular assemblies, and host/guest chemistry. These allow CTCs to be embraced in a wide range of innovative potential applications that include chemical sensing, semiconducting, gas and liquid adsorption/separation, catalysis, full-color display, and solid-state lighting. This review aims to provide a historic and comprehensive summary on CTCs and their extension to higher nuclearity complexes and coordination polymers from the perspectives of synthesis, structure, theoretical insight, and potential applications." @default.
- W3048499528 created "2020-08-18" @default.
- W3048499528 creator A5024743281 @default.
- W3048499528 creator A5038851564 @default.
- W3048499528 creator A5040755310 @default.
- W3048499528 creator A5050874957 @default.
- W3048499528 creator A5073743704 @default.
- W3048499528 date "2020-08-11" @default.
- W3048499528 modified "2023-10-16" @default.
- W3048499528 title "Coinage-Metal-Based Cyclic Trinuclear Complexes with Metal–Metal Interactions: Theories to Experiments and Structures to Functions" @default.
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