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- W3048503468 abstract "The electronic metal-support interactions that are well-known in metal-loaded metal oxides, are also disclosed in [email protected] According to the experimental and calculation results, the superior catalytic performance of [email protected](Ti) is mainly attributed to the higher ratio of Pd0/Pd2+ and electronic density of Pd nanoparticles which are triggered by stronger Lewis base sites and less Lewis acid sites of MIL-125(Ti) respectively. Therefore, the [email protected](Ti) catalyzed hydrogenation of nitroarenes and alkenes can be carried out in water using low Pd usage (0.12 mol%) with excellent selectivity under mild conditions (room temperature, 1 atm H2). Moreover, the aqueous catalytic system still stays in reactor by simple extraction, and can be reused without further treatment, thus resulting in low environmental factor." @default.
- W3048503468 created "2020-08-18" @default.
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- W3048503468 date "2020-11-01" @default.
- W3048503468 modified "2023-10-13" @default.
- W3048503468 title "The selective hydrogenation of nitroarenes and alkenes catalyzed by Pd@MOFs: The role of electronic interactions between Pd nanoparticles and MOFs on the reaction" @default.
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- W3048503468 doi "https://doi.org/10.1016/j.mcat.2020.111157" @default.
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