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- W3048598527 abstract "To increase proton conductivity of chitosan (CS) based polymer electrolyte membranes, a novel nanofiller-solid superacide SO42--TiO2 (STi) coated carbon nanotubes ([email protected]) are introduced into CS matrix to fabricate membranes for polymer electrolyte membrane fuel cells (PEMFCs). Owing to the STi coating, the dispersion ability of CNTs and interfacial bonding are obviously improved, hence, CNTs can more fully play their reinforcing role, which makes the CS/[email protected] composite membranes exhibit better mechanical properties than that of pure CS membrane. More importantly, STi possesses excellent proton transport ability and may create facile proton transport channels in the membranes with the help of high aspect ratio of CNTs. Particularly, the CS/[email protected] membrane (1 wt% [email protected] loading) obtains the highest proton conductivity of 4.2 × 10−2 S cm–1 at 80 °C, enhancing by 80% when compared with that of pure CS membrane. In addition, the [email protected] also confer the composite membranes low methanol crossover and outstanding cell performance. The maximum power density of the CS/[email protected] membrane is 60.7 mW cm−2 (5 M methanol concentration, 70 °C), while pure CS membrane produces the peak power density of only 39.8 mW cm−2." @default.
- W3048598527 created "2020-08-18" @default.
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- W3048598527 date "2020-10-01" @default.
- W3048598527 modified "2023-09-27" @default.
- W3048598527 title "Enhanced proton conductivities of chitosan-based membranes by inorganic solid superacid SO42−–TiO2 coated carbon nanotubes" @default.
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- W3048598527 doi "https://doi.org/10.1016/j.ijhydene.2020.07.157" @default.
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