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- W3048658303 abstract "Abstract A series of quaternized poly (arylene ether benzonitrile)s (QAxCN; x = percent quaternization) were synthesized for the vanadium redox flow battery (VRFB) application. The presence of highly polar nitrile groups incorporated in the quaternized polymer chain provides desirable polymer properties (low water uptake, high dimensional stability and low VO2+ permeability) without compromising ion conductivity. VRFB single cells using the aforementioned membranes showed excellent performance. The cell using a 15 μm-thick QA50CN membrane exhibited superior coulombic efficiency (98.2%) and comparable energy efficiency (86.5%) at 40 mA cm-2 compared to the single cell using Nafion-212 with a coulombic efficiency of 95.5% and an energy efficiency of 86.2%. The cell cycling stability and membrane oxidative stability data confirmed that the QAxCN membranes have the potential to replace Nafion membranes for energy storage in VRFB applications." @default.
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- W3048658303 date "2021-01-01" @default.
- W3048658303 modified "2023-10-17" @default.
- W3048658303 title "Quaternized poly(arylene ether benzonitrile) membranes for vanadium redox flow batteries" @default.
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- W3048658303 doi "https://doi.org/10.1016/j.memsci.2020.118565" @default.
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