FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3048669192> ?p ?o ?g. }

• W3048669192 endingPage "1821" @default.
• W3048669192 startingPage "1811" @default.
• W3048669192 abstract "ConspectusIn this Account, we demonstrate an increasing complexity approach to gain insight into the principal aspects of the surface and interface chemistry and catalysis of solid oxide fuel cell (SOFC) anode and electrolyte materials based on selected oxide, intermetallic, and metal–oxide systems at different levels of material complexity, as well as into the fundamental microkinetic reaction steps and intermediates at catalytically active surface and interface sites. To dismantle the complexity, we highlight our deconstructing step-by-step approach, which allows one to deduce synergistic properties of complex composite materials from the individual surface catalytic properties of the single constituents, representing the lowest complexity level: pure oxides and pure metallic materials. Upon mixing and doping the latter, directly leading to formation of intermetallic compounds/alloys in the case of metals and oxygen ion conductors/mixed ionic and electronic conductors for oxides, a second complexity level is reached. Finally, the introduction of an (inter)metall(ic)–(mixed) oxide interface leads to the third complexity level. A shell-like model featuring three levels of complexity with the unveiled surface and interface chemistry at its core evolves. As the shift to increased complexity decreases the number of different materials, the interconnections between the studied materials become more convoluted, but the resulting picture of surface chemistry becomes clearer. The materials featured in our investigations are all either already used technologically important or prospective components of SOFCs (such as yttria-stabilized zirconia, perovskites, or Ni–Cu alloys) or their basic constituents (e.g., ZrO2), or they are formed by reactions of other compounds (for instance, pyrochlores are thought to be formed at the YSZ/perovskite phase boundary). We elaborate three representative case studies based on ZrO2, Y2O3, and Y-doped ZrO2 in detail from all three complexity levels. By interconnection of results, we are able to derive common principles of the influence of surface and interface chemistry on the catalytic operation of SOFC anode materials. In situ measurements of the reactivity of water and carbon surface species on ZrO2- and Y2O3-based materials represent levels 1 and 2. The highest degree of complexity at level 3 is exemplified by combined surface science and catalytic studies of metal–oxide systems, oxidatively derived from intermetallic Cu–Zr and Pd–Zr compounds and featuring a large number of phases and interfaces. We show that only by appreciating insight into the basic building blocks of the catalyst materials at lower levels, a full understanding of the catalytic operation of the most complex materials at the highest level is possible." @default.
• W3048669192 created "2020-08-18" @default.
• W3048669192 creator A5032063733 @default.
• W3048669192 creator A5047698448 @default.
• W3048669192 creator A5060448951 @default.
• W3048669192 date "2020-08-12" @default.
• W3048669192 modified "2023-10-16" @default.
• W3048669192 title "Increasing Complexity Approach to the Fundamental Surface and Interface Chemistry on SOFC Anode Materials" @default.
• W3048669192 cites W1965495399 @default.
• W3048669192 cites W1970334998 @default.
• W3048669192 cites W1974473812 @default.
• W3048669192 cites W1987120623 @default.
• W3048669192 cites W2009221267 @default.
• W3048669192 cites W2013906682 @default.
• W3048669192 cites W2022312813 @default.
• W3048669192 cites W2030050020 @default.
• W3048669192 cites W2031254429 @default.
• W3048669192 cites W2041812377 @default.
• W3048669192 cites W2047778980 @default.
• W3048669192 cites W2049246365 @default.
• W3048669192 cites W2068494482 @default.
• W3048669192 cites W2071450802 @default.
• W3048669192 cites W2079013180 @default.
• W3048669192 cites W2087531382 @default.
• W3048669192 cites W2099061528 @default.
• W3048669192 cites W2125008527 @default.
• W3048669192 cites W2151040250 @default.
• W3048669192 cites W2171607748 @default.
• W3048669192 cites W2284825171 @default.
• W3048669192 cites W2285159712 @default.
• W3048669192 cites W2312569776 @default.
• W3048669192 cites W2344001102 @default.
• W3048669192 cites W2346795159 @default.
• W3048669192 cites W2418652451 @default.
• W3048669192 cites W2523703048 @default.
• W3048669192 cites W2536247728 @default.
• W3048669192 cites W2577408420 @default.
• W3048669192 cites W2587496948 @default.
• W3048669192 cites W2600666928 @default.
• W3048669192 cites W2613774419 @default.
• W3048669192 cites W2888941497 @default.
• W3048669192 cites W2891071647 @default.
• W3048669192 cites W2949302076 @default.
• W3048669192 cites W4211089104 @default.
• W3048669192 cites W4246328338 @default.
• W3048669192 doi "https://doi.org/10.1021/acs.accounts.0c00218" @default.
• W3048669192 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7497703" @default.
• W3048669192 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32786330" @default.
• W3048669192 hasPublicationYear "2020" @default.
• W3048669192 type Work @default.
• W3048669192 sameAs 3048669192 @default.
• W3048669192 citedByCount "2" @default.
• W3048669192 countsByYear W30486691922023 @default.
• W3048669192 crossrefType "journal-article" @default.
• W3048669192 hasAuthorship W3048669192A5032063733 @default.
• W3048669192 hasAuthorship W3048669192A5047698448 @default.
• W3048669192 hasAuthorship W3048669192A5060448951 @default.
• W3048669192 hasBestOaLocation W30486691921 @default.
• W3048669192 hasConcept C145148216 @default.
• W3048669192 hasConcept C147789679 @default.
• W3048669192 hasConcept C161790260 @default.
• W3048669192 hasConcept C171250308 @default.
• W3048669192 hasConcept C17525397 @default.
• W3048669192 hasConcept C178790620 @default.
• W3048669192 hasConcept C185592680 @default.
• W3048669192 hasConcept C191897082 @default.
• W3048669192 hasConcept C192562407 @default.
• W3048669192 hasConcept C2182769 @default.
• W3048669192 hasConcept C27501479 @default.
• W3048669192 hasConcept C2779851234 @default.
• W3048669192 hasConcept C2780026712 @default.
• W3048669192 hasConcept C544153396 @default.
• W3048669192 hasConcept C89395315 @default.
• W3048669192 hasConceptScore W3048669192C145148216 @default.
• W3048669192 hasConceptScore W3048669192C147789679 @default.
• W3048669192 hasConceptScore W3048669192C161790260 @default.
• W3048669192 hasConceptScore W3048669192C171250308 @default.
• W3048669192 hasConceptScore W3048669192C17525397 @default.
• W3048669192 hasConceptScore W3048669192C178790620 @default.
• W3048669192 hasConceptScore W3048669192C185592680 @default.
• W3048669192 hasConceptScore W3048669192C191897082 @default.
• W3048669192 hasConceptScore W3048669192C192562407 @default.
• W3048669192 hasConceptScore W3048669192C2182769 @default.
• W3048669192 hasConceptScore W3048669192C27501479 @default.
• W3048669192 hasConceptScore W3048669192C2779851234 @default.
• W3048669192 hasConceptScore W3048669192C2780026712 @default.
• W3048669192 hasConceptScore W3048669192C544153396 @default.
• W3048669192 hasConceptScore W3048669192C89395315 @default.
• W3048669192 hasFunder F4320320879 @default.
• W3048669192 hasFunder F4320321181 @default.
• W3048669192 hasIssue "9" @default.
• W3048669192 hasLocation W30486691921 @default.
• W3048669192 hasLocation W30486691922 @default.
• W3048669192 hasLocation W30486691923 @default.
• W3048669192 hasLocation W30486691924 @default.
• W3048669192 hasOpenAccess W3048669192 @default.
• W3048669192 hasPrimaryLocation W30486691921 @default.
• W3048669192 hasRelatedWork W1528683495 @default.

• next