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• W3048684279 abstract "Efficient access to chiral cyclopentadienyl esters from readily accessible chiral enynyl ester substrates is developed. Typically high levels of chirality transfer realized in this homogeneous gold catalysis are attributed to the intermediacy of a chiral bent allene gold complex. Cyclopentadienyl esters can be prepared in good yields and with excellent enantiomeric excesses. The synthetic utilities of the chiral cyclopentadienyl esters are demonstrated by the Diels–Alder reactions, fluorination, alkylation, and epoxidation without any notable erosion of enantiopurity." @default.
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• W3048684279 date "2020-08-10" @default.
• W3048684279 modified "2023-10-17" @default.
• W3048684279 title "Gold-Catalyzed Synthesis of Chiral Cyclopentadienyl Esters via Chirality Transfer" @default.
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• W3048684279 doi "https://doi.org/10.1021/acs.orglett.0c02293" @default.
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