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• W3048698639 endingPage "11904" @default.
• W3048698639 startingPage "11901" @default.
• W3048698639 abstract "The oxyhalide-based solid electrolyte Li2OHCl usually forms the thermodynamically stable orthorhombic phase at room temperature and shows poor lithium ionic conductivity. Above 35 °C, a structural phase transition into the cubic phase occurs and ionic conductivity is enhanced. In this work, mechanochemical synthesis of Li2OHCl is reported. The as-prepared Li2OHCl formed a cubic Pm3̅m structure and showed an ionic conductivity of 2.6 × 10–6 S cm–1 at 25 °C. Once the cubic phase was treated at 200 °C, the orthorhombic Pmc21 structure appeared at 25 °C and the ionic conductivity decreased down to 1.4 × 10–7 S cm–1. Formation of the metastable cubic phase could be explained in terms of low crystallinity of Li2OHCl derived from mechanochemical synthesis." @default.
• W3048698639 created "2020-08-18" @default.
• W3048698639 creator A5015366044 @default.
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• W3048698639 date "2020-08-12" @default.
• W3048698639 modified "2023-10-15" @default.
• W3048698639 title "Synthesis of the Metastable Cubic Phase of Li₂OHCl by a Mechanochemical Method" @default.
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• W3048698639 doi "https://doi.org/10.1021/acs.inorgchem.0c01631" @default.
• W3048698639 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32805990" @default.
• W3048698639 hasPublicationYear "2020" @default.
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