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• W3048793882 abstract "The role of avoided crossings for resonant x-ray Raman scattering is explored. The strong dependence of the electronic transition amplitudes on internuclear distance at avoided crossings causes new, and even anomalous, spectral features, and can bring about a breakdown of the generally accepted participator or spectator classification of the transitions. We report, and apply the theory on, an experimental observation of the electron decay of the N $1stackrel{ensuremath{rightarrow}}{s}{ensuremath{pi}}^{*}$ core-excited level in ${mathrm{N}}_{2}$ the ${B}^{2}{ensuremath{Sigma}}_{u}^{+}$ final state with peculiar, non-Franck-Condon, vibrational intensity distributions." @default.
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• W3048793882 date "2000-11-01" @default.
• W3048793882 modified "2023-10-18" @default.
• W3048793882 title "Resonant x-ray Raman Scattering involving avoided crossings in the final-state potential-energy curves" @default.
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• W3048793882 doi "https://doi.org/10.1103/physreva.62.062506" @default.
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