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- W3048877142 abstract "Anderson-type hexamolybdochromates [CoШ(bpy)3][CrMo6(OH)5 (OCH3)O18]·12H2O (1) and [CoШ(bpy)3][CrMo6(OH)6O18]·15H2O (2) were synthesized and characterized by elemental analysis, IR spectroscopy, thermal gravimetric analysis, and single-crystal X-ray diffraction. Compound 1 shows the first example that the B-type Anderson polyanion is functionalized by methyl through dehydration between a nonacidic proton and hydroxyl group of methanol. When the pH changed, 2 has been obtained and contains two types of [Cr(OH)6Mo6O18]3- anions with different Cr − O bond lengths. The synthesis of 1 indicates that B-type Anderson polyanions can be functionalized by methyl group under proper reaction conditions; this suggests a new route to functionalize polyoxometalates to form organic-inorganic hybrids." @default.
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- W3048877142 date "2020-08-13" @default.
- W3048877142 modified "2023-09-23" @default.
- W3048877142 title "Methylated B-type Anderson heteropolymolybdate: synthesis, structure, and magnetic properties" @default.
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- W3048877142 doi "https://doi.org/10.1080/00958972.2020.1805443" @default.
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